Li Xudong, Lin Min, Ali Imdad, Ali Ahmed, Irfan Muhammad, Soomro Toufique A, Choi Seung Ho, Yang Weimin, Li Haoyi, Rahman Saifur, Faraj Mursal Salim Nasar, Jazem Ghanim Abdulnour Ali, Alyahyawy Othman, Al Thagafi Morooj A
College of Mechanical and Electrical Engineering, Beijing University of Chemical Technology, Beijing 100029, P. R. China.
Beijing Advanced Innovation Center for Soft Matter Science and Engineering, College of Materials Science and Engineering, Beijing University of Chemical Technology, Beijing 100029, China.
ACS Omega. 2023 Jul 26;8(31):28924-28931. doi: 10.1021/acsomega.3c04546. eCollection 2023 Aug 8.
Temperature plays a crucial role in the preparation of polyvinyl chloride (PVC) gels for optical applications. Incorrect temperature selection can lead to various issues such as poor surface roughness, inadequate light transmission, and insufficient solution for optical devices. To address this challenge, this study focuses on the preparation of PVC gel samples by combining PVC powder ( = 3000), eco-friendly dibutyl adipate, and tetrahydrofuran at different stirring temperatures ranging from 40 to 70 °C. The PVC gel preparation process is categorized into four groups (40, 50, 60, and 70) based on the mixing temperatures, employing a controlled test method with specific temperature conditions. The prepared PVC gel samples are then subjected to analysis to evaluate various properties including surface morphology, tensile strength, light transmittance, and electrical response time. Among the samples, the PVC gel prepared at 60 °C (referred to as T60) exhibits excellent optical properties, with a transmittance of 91.2% and a tensile strength of 2.07 MPa. These results indicate that 60 °C is an optimal reaction temperature. Notably, the PVC gel microlenses produced at this temperature achieve their maximum focal length (ranging from -8 to -20 mm) within approximately 60 s, and they recover their initial state within around 80 s after the power is switched off. This focal length achievement is twice as fast as reported in previous studies on microlenses. It is observed that the reaction temperature significantly influences the solubility of the resin-based raw materials and the homogeneity of the gel. Consequently, these findings open up possibilities for utilizing PVC gel microlenses in novel commercial optics applications, thanks to their desirable properties.
温度在用于光学应用的聚氯乙烯(PVC)凝胶制备过程中起着至关重要的作用。不正确的温度选择可能会导致各种问题,如表面粗糙度差、透光率不足以及光学器件的溶液不足。为应对这一挑战,本研究聚焦于通过在40至70°C的不同搅拌温度下将PVC粉末(=3000)、环保型己二酸二丁酯和四氢呋喃混合来制备PVC凝胶样品。基于混合温度,PVC凝胶制备过程分为四组(40、50、60和70),采用具有特定温度条件的对照试验方法。然后对制备的PVC凝胶样品进行分析,以评估包括表面形态、拉伸强度、透光率和电响应时间在内的各种性能。在这些样品中,在60°C制备的PVC凝胶(称为T60)表现出优异的光学性能,透光率为91.2%,拉伸强度为2.07MPa。这些结果表明60°C是最佳反应温度。值得注意的是,在此温度下生产的PVC凝胶微透镜在大约60秒内达到其最大焦距(范围为-8至-20毫米),并且在断电后约80秒内恢复到初始状态。这一焦距的实现速度是先前关于微透镜研究报道速度的两倍。据观察,反应温度显著影响树脂基原材料的溶解度和凝胶的均匀性。因此,由于其理想的性能,这些发现为在新型商业光学应用中利用PVC凝胶微透镜开辟了可能性。