Kapon Yael, Kammerbauer Fabian, Yochelis Shira, Kläui Mathias, Paltiel Yossi
Institute of Applied Physics, Faculty of Sciences, The Hebrew University of Jerusalem, Jerusalem 9190401, Israel.
Institute of Physics, Johannes Gutenberg University Mainz, Staudingerweg 7, 55128 Mainz, Germany.
J Chem Phys. 2023 Aug 14;159(6). doi: 10.1063/5.0159351.
Chiral molecules have the potential for creating new magnetic devices by locally manipulating the magnetic properties of metallic surfaces. When chiral polypeptides chemisorb onto ferromagnets, they can induce magnetization locally by spin exchange interactions. However, direct imaging of surface magnetization changes induced by chiral molecules was not previously realized. Here, we use magneto-optical Kerr microscopy to image domains in thin films and show that chiral polypeptides strongly pin domains, increasing the coercive field locally. In our study, we also observe a rotation of the easy magnetic axis toward the out-of-plane, depending on the sample's domain size and the adsorption area. These findings show the potential of chiral molecules to control and manipulate magnetization and open new avenues for future research on the relationship between chirality and magnetization.
手性分子具有通过局部操纵金属表面的磁性能来制造新型磁性器件的潜力。当手性多肽化学吸附到铁磁体上时,它们可以通过自旋交换相互作用局部诱导磁化。然而,此前尚未实现对手性分子诱导的表面磁化变化进行直接成像。在这里,我们使用磁光克尔显微镜对薄膜中的磁畴进行成像,并表明手性多肽强烈固定磁畴,局部增加矫顽场。在我们的研究中,我们还观察到易磁化轴朝着面外方向旋转,这取决于样品的磁畴尺寸和吸附面积。这些发现表明手性分子在控制和操纵磁化方面的潜力,并为未来关于手性与磁化之间关系的研究开辟了新途径。