Zhao Shuya, Chen Zhaoyang, Liu Huimin, Qi Lu, Zheng Zhiqiang, Luan Xiaoyu, Gao Yaqi, Liu Runyu, Yan Jiayu, Bu Fanle, Xue Yurui, Li Yuliang
Shandong Provincial Key Laboratory for Science of Material Creation and Energy Conversion, Science Center for Material Creation and Energy Conversion, School of Chemistry and Chemical Engineering, Institute of Frontier and Interdisciplinary Science, Shandong University, 250100, Jinan, China.
CAS Key Laboratory of Organic Solids, Institute of Chemistry, Chinese Academy of Sciences, 100190, Beijing, China.
ChemSusChem. 2023 Dec 7;16(23):e202300861. doi: 10.1002/cssc.202300861. Epub 2023 Sep 22.
Graphdiyne, a sp/sp -cohybridized two-dimensional all- carbon material, has many unique and fascinating properties of alkyne-rich structures, large π conjugated system, uniform pores, specific unevenly-distributed surface charge, and incomplete charge transfer properties provide promising potential in practical applications including catalysis, energy conversion and storage, intelligent devices, life science, photoelectric, etc. These superior advantages have made graphdiyne one of the hottest research frontiers of chemistry and materials science and produced a series of original and innovative research results in the fundamental and applied research of carbon materials. In recent years, considerable advances have been made toward the development of graphdiyne-based multiscale catalysts for nitrogen fixation and ammonia synthesis at room temperatures and ambient pressures. This review aims to provide a comprehensive update in regard to the synthesis of graphdiyne-based multiscale catalysts and their applications in the synthesis of ammonia. The unique features of graphdiyne are highlighted throughout the review. Finally, it concludes with the discussion of challenges and future perspectives relating to graphdiyne.
石墨炔是一种sp/sp 杂化的二维全碳材料，具有许多独特且引人入胜的性质，如富含炔烃的结构、大π共轭体系、均匀的孔隙、特定的表面电荷不均匀分布以及不完全电荷转移性质，这使其在催化、能量转换与存储、智能设备、生命科学、光电等实际应用中具有广阔的潜在应用前景。这些卓越的优势使石墨炔成为化学和材料科学领域最热门的研究前沿之一，并在碳材料的基础研究和应用研究中产生了一系列原创性和创新性的研究成果。近年来，在室温及常压下用于固氮和合成氨的石墨炔基多尺度催化剂的开发方面取得了显著进展。本综述旨在全面更新关于石墨炔基多尺度催化剂的合成及其在氨合成中的应用的相关内容。在整个综述中突出了石墨炔的独特特征。最后，对与石墨炔相关的挑战和未来展望进行了讨论。
