Towards ductile and high barrier poly(L-lactic acid) ultra-thin packaging film by regulating chain structures for efficient preservation of cherry tomatoes.

The irreconcilable paradox between barrier performance and ductility is a "stumbling block" restricting the development of poly(L-lactic acid) (PLLA) films in the packaging industry. In this work, we reported the fabrication of an ultra-thin PLLA-based film with barrier properties and ductility by adjusting the polarity and conformational behavior of the polymer chains. Firstly, a novel unsaturated poly(L-lactic acid-co-butyrate itaconate) P(LA-BI) copolymer containing CC double bonds was synthesized using melt polycondensation. The results reveal that the addition of 60 % of P(LA-BI) enables PLLA film to achieve an elongation at a break of 83.6 % due to P(LA-BI) containing partially branched structures, which resulted in the polymer chains being arranged more in a high-energy gg conformer. Meanwhile, because of the large number of CO polar groups in P(LA-BI), PLLA/P(LA-BI) film show CO and O permeability coefficients (CDP and OP) of 1.8 and 0.45 × 10 g·m·m·h·Pa respectively, which means that it has excellent gas barrier properties. Moreover, PLLA/P(LA-BI) film shows a 33.3 % increase in CO/O ratio and an excellent ultraviolet (UV) barrier performance compared to neat PLLA. Preservation results suggested that the CO and O levels within the package could be regulated by varying the amount of P(LA-BI) added. Among them, PLLA/P(LA-BI) film generated a more desirable CO and O atmosphere for cherry tomatoes preservation, which was reflected by the delaying of senescence, discoloration, and decay, inhibition of oxidative cell damage through reduced malondialdehyde production, and maintenance of nutritional and flavor substances in cherry tomatoes. This PLLA-based film offers the advantages of operational simplicity, environmental friendliness, and inexpensive cost, making it great promising for food preservation and other applications requiring barrier properties and ductility.