Colmenares Pedro J
Departamento de Química, Universidad de Los Andes, Mérida 5101, Venezuela.
Phys Rev E. 2023 Jul;108(1-1):014115. doi: 10.1103/PhysRevE.108.014115.
This article revisits the fluctuation-dissipation relationship of a generalized Brownian particle constrained in a harmonic potential and immersed in a thermal bath whose degrees of freedom also interact with the external field. The generalized Langevin equation put forth herein keeps its original form. The different terms now depend on a compound strength related to those of the field and bath oscillators. The resulting theorem keeps Kubo's original form with the memory kernel depending on the frequency of the field. It has the consequence that friction is not a constant but is a function of the field frequency as predicted by molecular dynamics simulations. The position particle distribution and the Fokker-Planck equation associated with the generalized Langevin equation are also derived.
本文重新审视了一个广义布朗粒子的涨落耗散关系,该粒子受限于简谐势并浸没在一个热浴中,热浴的自由度也与外场相互作用。本文提出的广义朗之万方程保持其原始形式。现在不同的项取决于与场和热浴振荡器相关的复合强度。所得定理保持了久保的原始形式,其中记忆核取决于场的频率。其结果是,摩擦力不是常数,而是如分子动力学模拟所预测的那样是场频率的函数。还推导了与广义朗之万方程相关的位置粒子分布和福克 - 普朗克方程。