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用于处理染料废水的多孔聚合物磁性吸附剂。

Porous polymer magnetic adsorbents for dye wastewater treatment.

机构信息

Key Laboratory of Specially Functional Polymeric Materials and Related Technology (Ministry of Education), School of Materials Science and Engineering, East China University of Science and Technology, 130, Meilong Road, Shanghai, 200237, People's Republic of China.

出版信息

Environ Sci Pollut Res Int. 2023 Sep;30(43):97147-97159. doi: 10.1007/s11356-023-29102-7. Epub 2023 Aug 16.

Abstract

Dye wastewater discharged from industries has caused serious environmental problems. The recent decade has witnessed adsorption technology emerging as an advanced dye wastewater treatment method with great potential Therefore, we fabricated two kinds of magnetic porous adsorbents (HSF and HSVF) with different specific surface areas and activity sites. Both of which exhibit excellent performance with remarkable dye adsorption capacities, especially HSVF. We further investigated their adsorption kinetic and isotherm in detail. Therein, HSVF showed a nice desorption capacity, and it could be recycled rapidly by magnetism, which exhibited the advantages of effective, easy operation, and low cost. In addition, their adsorption kinetic and isotherm were further studied and compared in detail. The results revealed that introducing strong active sites could improve both the adsorption capacity and rate effectively even though sacrificing part of specific surface areas, indicating that active sites might play a dominant role during the dye adsorption process.

摘要

染料废水排放造成了严重的环境问题。近十年来,吸附技术作为一种有前途的染料废水处理方法已经崭露头角。因此,我们制备了两种具有不同比表面积和活性位的磁性多孔吸附剂(HSF 和 HSVF)。这两种吸附剂都表现出了优异的染料吸附性能,尤其是 HSVF。我们进一步详细研究了它们的吸附动力学和吸附等温线。其中,HSVF 表现出了良好的解吸能力,并且可以通过磁性快速回收,这表现出了高效、易操作和低成本的优点。此外,我们还进一步详细研究和比较了它们的吸附动力学和吸附等温线。结果表明,引入强活性位可以有效地提高吸附容量和速率,即使牺牲部分比表面积也是如此,这表明活性位在染料吸附过程中可能起主导作用。

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