Cao Pengke, Ma Qingwen, Zha Mingming, Zhang Jian, Huo Zijian
School of Water Conservancy and Transportation, Zhengzhou University, Zhengzhou 450001, China.
Materials (Basel). 2023 Aug 16;16(16):5646. doi: 10.3390/ma16165646.
The special particle grading properties of silt lead to the strong water sensitivity and low soil strength of silt sites, many of which are severely damaged and urgently need to be repaired. This article takes the powder soil from a certain burial site area in Xizhu Village, Luoyang as the research object, which is improved by adding nanosilica and potassium methylsilicate. The modified soil is studied through mechanical and waterproof performance tests, and the mechanism of action of the modified material is analyzed through SEM and XRD. The experimental results show that the mechanical properties and waterproof properties of the composite modified soil were improved when the nanosilica content was 2% and the potassium methylsilicate content was 0.5%; the durability of the composite modified soil is improved, making this the optimum ratio. The mechanical properties and water resistance of the silty soil were significantly improved by adding the appropriate amount of nanosilica and potassium methylsilicate. Nanosilica can be evenly dispersed in the soil matrix, absorb a small amount of water to form a gel state, fill the pores in the silt aggregates, and improve soil compactness. In addition, nanosilica aggregates can attach to the surface of the soil particles and extend from the particle surface to the particle edge. By increasing the contact between soil particles and increasing the particle size, the mechanical properties of the modified soil are improved. When potassium methylsilicate solution is added to the soil, it reacts with water and carbon dioxide, decomposes into methylsilicate, and quickly generates a polymethylsiloxane film to cover the surface of soil particles, forming a waterproof film on the surface and thereby improving the waterproof performance of modified soil. Our research results can provide a reference for the restoration and protection of silty and silt-like sites. The next step is to apply the composite modified soil in engineering restoration through field tests in order to study the repairing ability of composite modified soil and its actual protective effects.
粉质土特殊的颗粒级配特性导致粉质土场地具有很强的水敏感性和较低的土体强度,其中许多场地遭到严重破坏,急需修复。本文以洛阳西朱村某埋藏场地的粉土为研究对象,通过添加纳米二氧化硅和硅酸钾对其进行改良。通过力学性能和防水性能试验对改良后的土进行研究,并通过扫描电子显微镜(SEM)和X射线衍射仪(XRD)分析改良材料的作用机理。试验结果表明,当纳米二氧化硅含量为2%、硅酸钾含量为0.5%时,复合改良土的力学性能和防水性能得到改善;复合改良土的耐久性得到提高,此为最佳配比。添加适量纳米二氧化硅和硅酸钾后,粉质土的力学性能和抗水性显著提高。纳米二氧化硅能够均匀分散在土基质中,吸收少量水分形成凝胶态,填充粉质土团聚体中的孔隙,提高土体密实度。此外,纳米二氧化硅团聚体可附着在土颗粒表面,并从颗粒表面延伸至颗粒边缘,通过增加土颗粒间的接触并增大颗粒尺寸,提高改良土的力学性能。当向土中加入硅酸钾溶液时,其与水和二氧化碳反应,分解生成硅酸甲酯,并迅速生成聚甲基硅氧烷膜覆盖在土颗粒表面,在表面形成防水膜,从而提高改良土的防水性能。研究结果可为粉质土及类粉质土场地的修复与保护提供参考。下一步将通过现场试验将复合改良土应用于工程修复中,以研究复合改良土的修复能力及其实际保护效果。