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负载TiO的多壁碳纳米管作为高性能填料用于制备纳米复合膜以规模化光催化降解水中双酚A

MWCNTs Decorated with TiO as Highly Performing Filler in the Preparation of Nanocomposite Membranes for Scalable Photocatalytic Degradation of Bisphenol A in Water.

作者信息

Tursi Antonio, Beneduci Amerigo, Nicotera Isabella, Simari Cataldo

机构信息

Department of Chemistry and Chemical Technologies, University of Calabria, Via P. Bucci, Cubo 15D, 87036 Arcavacata di Rende, Italy.

SIRiA S.r.l.-Servizi Integrati e Ricerche per l'Ambiente, c/o Department of Chemistry and Chemical Technologies, Spin-Off of the University of Calabria, Via P. Bucci, Cubo 15D, 87036 Arcavacata di Rende, Italy.

出版信息

Nanomaterials (Basel). 2023 Aug 13;13(16):2325. doi: 10.3390/nano13162325.

Abstract

Bisphenol A (BPA), an endocrine-disrupting compound with estrogenic behavior, is of great concern within the scientific community due to its high production levels and increasing concentration in various surface aquifers. While several materials exhibit excellent capacity for the photocatalytic degradation of BPA, their powdered nature and poor chemical stability render them unsuitable for practical application in large-scale water decontamination. In this study, a new class of nanocomposite membranes based on sulfonated polyethersulfone (sPES) and multiwalled carbon nanotubes decorated with TiO nanoparticles (MWCNTs-TiO) were investigated as efficient and scalable photocatalysts for the photodegradation of BPA in aqueous solutions. The MWCNTs-TiO hybrid material was prepared through a facile and inexpensive hydrothermal method and extensively characterized by XRD, Raman, FTIR, BET, and TGA. Meanwhile, nanocomposite membranes at different filler loadings were prepared by a simple casting procedure. Swelling tests and PFG NMR analyses provided insights into the impact of filler introduction on membrane hydrophilicity and water molecular dynamics, whereas the effectiveness of the various photocatalysts in BPA removal was monitored using HPLC. Among the different MWCNTs-TiO content nanocomposites, the one at 10 wt% loading (sP-MT) showed the best photoactivity. Under UV irradiation at 254 nm and 365 nm for 240 min, photocatalytic oxidation of 5 mg/L bisphenol A by sP-MT resulted in 91% and 82% degradation, respectively. Both the effect of BPA concentration and the membrane regenerability were evaluated, revealing that the sP-MT maintained its maximum BPA removal capability over more than 10 cycles. Our findings indicate that sP-MT nanocomposite membranes are versatile, scalable, efficient, and highly reusable photocatalysts for the degradation of BPA, as well as potentially for other endocrine disruptors.

摘要

双酚A(BPA)是一种具有雌激素行为的内分泌干扰化合物,因其产量高且在各种地表水层中的浓度不断增加,在科学界引起了极大关注。虽然几种材料对BPA具有优异的光催化降解能力,但其粉末状性质和较差的化学稳定性使其不适用于大规模水净化的实际应用。在本研究中,研究了一类基于磺化聚醚砜(sPES)和负载TiO纳米颗粒的多壁碳纳米管(MWCNTs-TiO)的新型纳米复合膜,作为水溶液中BPA光降解的高效且可扩展的光催化剂。MWCNTs-TiO杂化材料通过简便且廉价的水热法制备,并通过XRD、拉曼光谱、FTIR、BET和TGA进行了广泛表征。同时,通过简单的浇铸程序制备了不同填料负载量的纳米复合膜。溶胀试验和脉冲场梯度核磁共振(PFG NMR)分析深入了解了填料引入对膜亲水性和水分子动力学的影响,而使用高效液相色谱(HPLC)监测了各种光催化剂去除BPA的效果。在不同MWCNTs-TiO含量的纳米复合材料中,负载量为10 wt%的复合材料(sP-MT)表现出最佳的光活性。在254 nm和365 nm的紫外光照射下240分钟,sP-MT对5 mg/L双酚A的光催化氧化分别导致91%和82%的降解率。评估了BPA浓度的影响和膜的再生能力,结果表明sP-MT在超过10个循环中保持了其最大的BPA去除能力。我们的研究结果表明,sP-MT纳米复合膜是用于降解BPA以及潜在用于其他内分泌干扰物的通用、可扩展、高效且高度可重复使用的光催化剂。

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