Gold nanobipyramid colorimetric sensing array for the differentiation of strong aroma-type baijiu with different geographical origins.

It is of great significance to quickly and effectively distinguish strong aroma-type baijiu (SAB) with the largest baijiu market share and the most extensive production regions. Colorimetric sensor arrays based on gold nanobipyramids (AuNBPs) with extraordinary plasmonic properties were constructed for the differentiation of SAB from different geographical origins. The sensing strategy was based on silver deposition on different morphologies of AuNBPs under different reducing conditions containing amino or hydroxyl groups. The deposition process can be effective for distinguishing differences in baijiu due to the chemical interaction between the trace ingredients in baijiu and reductants. The colorimetric sensor arrays were implemented for the response of the main ingredients and further used for the differentiation of SAB from different regions by linear discriminant analysis. The results showed that the sensing strategy had excellent performance in distinguishing SAB from different origins, and provides a promising application strategy for baijiu quality control.