Neural network-based performance assessment of one- and two-liquid phase biotrickling filters for the removal of a waste-gas mixture containing methanol, α-pinene, and hydrogen sulfide.

The performance of one- and two-liquid phase biotrickling filters (OLP/TLP-BTFs) treating a mixture of gas-phase methanol (M), α-pinene (P), and hydrogen sulfide (H) was assessed using artificial neural network (ANN) modeling. The best ANN models with the topologies 3-9-3 and 3-10-3 demonstrated an exceptional capacity for predicting the performance of O/TLP-BTFs, with R > 99%. The analysis of causal index (CI) values for the model of OLP-BTF revealed a negative impact of M on P removal (CI = -2.367), a positive influence of P and H on M removal (CI = +7.536 and CI = +3.931) and a negative effect of H on P removal (CI = -1.640). The addition of silicone oil in TLP-BTF reduced the negative impact of M and H on P degradation (CI = -1.261 and CI = -1.310, respectively) compared to the OLP-BTF. These findings suggested that silicone oil had the potential to improve P availability to the biofilm by increasing the concentration gradient of P between the air/gas and aqueous phases. Multi-objective particle swarm optimization (MOPSO) suggested an optimum operational condition, i.e. inlet M, P, and H concentrations of 1.0, 1.1, and 0.3 g m, respectively, with elimination capacities (ECs) of 172.1, 26.5, and 0.025 g m h for OLP-BTF. Likewise, one of the optimum operational conditions for TLP-BTF is achievable at inlet concentrations of 4.9, 1.7, and 0.8 g m, leading to the optimum ECs of 299.7, 52.9, and 0.072 g m h for M, P, and H, respectively. These results provide important insights into the treatment of complex waste gas mixtures, addressing the interactions between the pollutant removal characteristics in OLP/TLP-BTFs and providing novel approaches in the field of biological waste gas treatment.