Delaporte Solène, Abánades Lázaro Isabel, López-Cabrelles Javier, Mazarakioti Eleni C, Chebourou Sarah, Vitórica-Yrezábal Iñigo J, Giménez-Marqués Mónica, Mínguez Espallargas Guillermo
Instituto de Ciencia Molecular (ICMol), Universitat de València, Catedrático José Beltrán 2, 46980 Paterna, Spain.
ENS Paris-Saclay, Département de Chimie, 4 Av. des Sciences, 91190 Gif-sur-Yvette, France.
Dalton Trans. 2023 Nov 7;52(43):15682-15687. doi: 10.1039/d3dt02482b.
A family of robust and stable molybdenum-based metal-organic cages have been obtained based on the [MoO(μ-O)] secondary building unit. The resulting cages are decorated with different pyrdine derivatives that impart structural stability, resulting in the structural elucidation of the activated cage with single-crystal diffraction. The chemical robustness of the cage is also demonstrated by the post-synthetic modification of the cage, which allows the exchange of the pyridine derivatives without rupture of the cage.
基于[MoO(μ-O)]二级结构单元，已获得了一系列坚固且稳定的钼基金属有机笼。所得的笼用不同的吡啶衍生物进行修饰，这些衍生物赋予结构稳定性，从而通过单晶衍射对活化笼进行结构解析。笼的化学稳定性还通过笼的后合成修饰得到证明，该修饰允许吡啶衍生物进行交换而不破坏笼。
