Benkhaled Belkacem Tarek, Chaix Arnaud, Gomri Chaimaa, Buys Sébastien, Namar Nabil, Sehoulia Nadine, Jadhav Rohitkumar, Richard Jason, Lichon Laure, Nguyen Christophe, Gary-Bobo Magali, Semsarilar Mona
IEM, Univ Montpellier, CNRS, ENSCM, Institut Européen des Membranes, Montpellier 34095, France.
IBMM, Univ Montpellier, CNRS, ENSCM, Institut des Biomolécules Max Mousseron, Montpellier 34095, France.
ACS Appl Mater Interfaces. 2023 Sep 13;15(36):42942-42953. doi: 10.1021/acsami.3c08061. Epub 2023 Aug 30.
Herein, we report for the first time a biocompatible cross-linked trianglamine (Δ) network for the efficient iodine removal from the vapor phase, water, and seawater. In the vapor phase, the cross-linked network could capture 6 g g of iodine, ranking among the most performant materials for iodine vapor capture. In the liquid phase, this cross-linked network is also capable of capturing iodine at high rates from aqueous media (water and seawater). This network displayed fast adsorption kinetics, and they are fully recyclable. This study reveals the high affinity of iodine for the intrinsic cavity of the trianglamine. The synthesized materials are extremely interesting since they are environmentally friendly and inexpensive and the synthesis could easily be scaled up to be used as the material of choice in response to accidents in the nuclear industry.
在此,我们首次报道了一种生物相容性交联三角胺(Δ)网络,用于从气相、水和海水中高效去除碘。在气相中,交联网络能够捕获6 gg的碘,跻身于碘蒸气捕获性能最佳的材料之列。在液相中,这种交联网络也能够从水性介质(水和海水)中高速捕获碘。该网络显示出快速的吸附动力学,并且它们可完全回收利用。这项研究揭示了碘对三角胺固有空腔的高亲和力。合成的材料极具吸引力,因为它们环保且廉价,并且合成过程可以轻松扩大规模,用作应对核工业事故的首选材料。