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掺镝 SrLaZrO:Eu 荧光粉的可调谐暖白光发射和能量传递。

Tunable warm white light emission and energy transfer of Dy co-doped Sr LaZrO :Eu phosphors.

机构信息

College of Chemistry and Environmental Science, Inner Mongolia Normal University, Hohhot, China.

出版信息

Luminescence. 2024 Jan;39(1):e4582. doi: 10.1002/bio.4582. Epub 2023 Dec 20.

Abstract

Eu ,Dy co-doped Sr LaZrO -based phosphors were prepared through a sol-gel method. Through characterization, it was found that the Sr LaZrO -based fluorescent powder co-doped with Eu and Dy had a cubic structure. At an excitation wavelength of 290 nm, the substrate Sr LaZrO exhibited strong blue emission at 468 nm, and the Sr LaZrO :18%Eu phosphor exhibited a strong red emission peak at 612 nm. When the doping amount of Dy was 5, 8, 12, 15, or 18%, the Sr LaZrO :18%Eu phosphor changed from an orange-red light, to a warm white light, and to a cold white light. According to the emission spectra, the emission intensities of the substrates Sr LaZrO and Sr LaZrO :Eu decreased with increasing Dy concentration, confirming the energy transfer between the host Sr LaZrO -Eu ,Dy , and resulting in a lower CCT value, with significantly improved white light emission.

摘要

采用溶胶-凝胶法制备了 Eu、Dy 共掺杂 SrLaZrO 基荧光粉。通过表征发现,Eu、Dy 共掺杂 SrLaZrO 基荧光粉具有立方结构。在激发波长为 290nm 时,基质 SrLaZrO 在 468nm 处呈现出较强的蓝光发射,SrLaZrO:18%Eu 荧光粉在 612nm 处呈现出较强的红光发射峰。当 Dy 的掺杂量为 5%、8%、12%、15%或 18%时,SrLaZrO:18%Eu 荧光粉的颜色从橙红色变为暖白色,再变为冷白色。根据发射光谱,基质 SrLaZrO 和 SrLaZrO:Eu 的发射强度随 Dy 浓度的增加而降低,证实了基质 SrLaZrO-Eu、Dy 之间的能量传递,从而导致 CCT 值降低,白光发射显著增强。

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