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具有优化阻抗匹配和协同效应的海绵状三元纳米复合材料用于宽带和强微波吸收。

Spongy ternary nano-composites with optimized impedance matching and synergistic effect for broadband and strong microwave absorption.

作者信息

Li Shanxin, Sun Yijing, Jiang Xuzhou, Yu Hongying

机构信息

School of Materials, Sun Yat-sen University & Southern Marine Science and Engineering Guangdong Laboratory (Zhuhai), Zhuhai 519082, PR China.

Sino-French Institute of Nuclear Engineering & Technology, Sun Yat-Sen University, Zhuhai 519082, PR China.

出版信息

J Colloid Interface Sci. 2023 Dec 15;652(Pt B):1197-1207. doi: 10.1016/j.jcis.2023.08.135. Epub 2023 Aug 22.

Abstract

To counter the negative effects of electromagnetic radiation on the immunity of precision instruments, the stealthiness of military equipment, and human health, the preparation of porous multi-component nano-composites is considered an effective strategy to obtain efficient microwave absorption. In this work, the spongy ternary nano-composites (STC) with large specific surface area (SSA) and pore volume obtained by adjusting the calcination temperature, the porous effectively improves the impedance matching. The ternary composition of FeCo/FeNi/C, large SSA and pore volume provide abundant specific surface/interface for polarization and magnetization, the continuous conductive network is established, the strong dielectric and magnetic loss achieve a synergistic effect, realizing strong absorption in the low-frequency, greatly reducing the minimum reflection loss (RL, -56.37 dB) and broadening the effective absorption bandwidth (EAB, 7.45 GHz). The microwave absorption mechanism has been analyzed in detail and its great potential for practical applications has been verified by RCS signal simulations. This research provides an effective method for fabricating high-performance ternary nano-composite microwave absorbers.

摘要

为了对抗电磁辐射对精密仪器的免疫力、军事装备的隐身性以及人类健康的负面影响,制备多孔多组分纳米复合材料被认为是获得高效微波吸收的有效策略。在这项工作中,通过调节煅烧温度获得具有大比表面积(SSA)和孔体积的海绵状三元纳米复合材料(STC),多孔结构有效地改善了阻抗匹配。FeCo/FeNi/C的三元组成、大比表面积和孔体积为极化和磁化提供了丰富的比表面/界面,建立了连续的导电网络,强介电和磁损耗实现协同效应,在低频实现强吸收,大大降低了最小反射损耗(RL,-56.37 dB)并拓宽了有效吸收带宽(EAB,7.45 GHz)。详细分析了微波吸收机制,并通过RCS信号模拟验证了其在实际应用中的巨大潜力。本研究为制备高性能三元纳米复合微波吸收剂提供了一种有效方法。

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