具有类罗丹明配体的多功能双炔基铂（II）联吡啶配合物，具有近红外磷光和延迟荧光。
Multifunctional bisalkynylplatinum(II) bipyridine complexes with rhodamine-like ligands featuring near-infrared phosphorescence and delayed fluorescence.
作者信息
Zhao Shunan, Song Jianfeng, Wong Keith Man-Chung
机构信息
School of Chemistry and Chemical Engineering, Harbin Institute of Technology, Harbin 15001, China.
Department of Chemistry, Southern University of Science and Technology, No. 1088 Xueyuan Blvd., Shenzhen, 518055, P. R. China.
出版信息
Chem Commun (Camb). 2023 Sep 19;59(75):11272-11275. doi: 10.1039/d3cc03775d.
A series of platinum(II) bipyridine complexes with two rhodamine-like alkynyl (Rhodyne) ligands were developed to show chemo-induced "ON-OFF" switching capabilities with exceptional near-infrared phosphorescence and delayed fluorescence. This study contributes to the design of versatile photosensitizers with multiple functionalities, including metal ion and biomolecule sensing, photodynamic therapy, and optoelectronics.
一系列含有两个罗丹明类炔基（Rhodyne）配体的铂（II）联吡啶配合物被开发出来，以展现化学诱导的“开-关”切换能力，并具有出色的近红外磷光和延迟荧光。这项研究有助于设计具有多种功能的多功能光敏剂，包括金属离子和生物分子传感、光动力疗法及光电子学。
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