• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利:CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法,用中文像聊天一样搜索,搜遍4000万医学文献。AI智能推荐,让科研检索更轻松。

立即免费搜索

文件翻译

保留排版,准确专业,支持PDF/Word/PPT等文件格式,支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述,25分钟生成高质量综述,智能提取关键信息,辅助科研写作。

立即免费体验

具有类罗丹明配体的多功能双炔基铂(II)联吡啶配合物,具有近红外磷光和延迟荧光。

Multifunctional bisalkynylplatinum(II) bipyridine complexes with rhodamine-like ligands featuring near-infrared phosphorescence and delayed fluorescence.

作者信息

Zhao Shunan, Song Jianfeng, Wong Keith Man-Chung

机构信息

School of Chemistry and Chemical Engineering, Harbin Institute of Technology, Harbin 15001, China.

Department of Chemistry, Southern University of Science and Technology, No. 1088 Xueyuan Blvd., Shenzhen, 518055, P. R. China.

出版信息

Chem Commun (Camb). 2023 Sep 19;59(75):11272-11275. doi: 10.1039/d3cc03775d.

DOI:10.1039/d3cc03775d
PMID:37664951
Abstract

A series of platinum(II) bipyridine complexes with two rhodamine-like alkynyl (Rhodyne) ligands were developed to show chemo-induced "ON-OFF" switching capabilities with exceptional near-infrared phosphorescence and delayed fluorescence. This study contributes to the design of versatile photosensitizers with multiple functionalities, including metal ion and biomolecule sensing, photodynamic therapy, and optoelectronics.

摘要

一系列含有两个罗丹明类炔基(Rhodyne)配体的铂(II)联吡啶配合物被开发出来,以展现化学诱导的“开-关”切换能力,并具有出色的近红外磷光和延迟荧光。这项研究有助于设计具有多种功能的多功能光敏剂,包括金属离子和生物分子传感、光动力疗法及光电子学。

相似文献

1
Multifunctional bisalkynylplatinum(II) bipyridine complexes with rhodamine-like ligands featuring near-infrared phosphorescence and delayed fluorescence.具有类罗丹明配体的多功能双炔基铂(II)联吡啶配合物,具有近红外磷光和延迟荧光。
Chem Commun (Camb). 2023 Sep 19;59(75):11272-11275. doi: 10.1039/d3cc03775d.
2
The switchable phosphorescence and delayed fluorescence of a new rhodamine-like dye through allenylidene formation in a cyclometallated platinum(ii) system.一种新型罗丹明类染料在环金属化铂(II)体系中通过亚烷基丙二烯形成实现的可切换磷光和延迟荧光。
Chem Sci. 2021 Jul 7;12(33):11056-11064. doi: 10.1039/d1sc02787e. eCollection 2021 Aug 25.
3
Platinum(II) Ring-Fused Chlorins as Near-Infrared Emitting Oxygen Sensors and Photodynamic Agents.铂(II)环稠合二氢卟吩作为近红外发光氧传感器和光动力剂。
ACS Med Chem Lett. 2017 Feb 22;8(3):310-315. doi: 10.1021/acsmedchemlett.6b00476. eCollection 2017 Mar 9.
4
Room temperature phosphorescence from ruthenium(II) complexes bearing conjugated pyrenylethynylene subunits.含有共轭芘乙炔亚基的钌(II)配合物的室温磷光。
Inorg Chem. 2004 Sep 20;43(19):6083-92. doi: 10.1021/ic049288+.
5
Osmium complexes with tridentate 6-pyrazol-3-yl 2,2'-bipyridine ligands: coarse tuning of phosphorescence from the red to the near-infrared region.含有三齿6-吡唑-3-基-2,2'-联吡啶配体的锇配合物:从红色到近红外区域磷光的粗调谐
Chem Asian J. 2007 Jan 8;2(1):155-63. doi: 10.1002/asia.200600289.
6
π-Expansive Heteroleptic Ruthenium(II) Complexes as Reverse Saturable Absorbers and Photosensitizers for Photodynamic Therapy.作为光动力疗法的反向饱和吸收剂和光敏剂的π-扩展异核钌(II)配合物
Inorg Chem. 2017 Mar 20;56(6):3245-3259. doi: 10.1021/acs.inorgchem.6b02624. Epub 2017 Mar 6.
7
Unusual Circularly Polarized and Aggregation-Induced Near-Infrared Phosphorescence of Helical Platinum(II) Complexes with Tetradentate Salen Ligands.具有四齿席夫碱配体的螺旋型铂(II)配合物的异常圆偏振和聚集诱导近红外磷光。
Chemistry. 2018 May 17;24(28):7128-7132. doi: 10.1002/chem.201801414. Epub 2018 Apr 26.
8
Visible light-harvesting trans bis(alkylphosphine) platinum(II)-alkynyl complexes showing long-lived triplet excited states as triplet photosensitizers for triplet-triplet annihilation upconversion.可见光敏化反式双(烷基膦)铂(II)-炔基配合物,作为三重态-三重态湮灭上转换的三重态光敏剂,具有长寿命三重态激发态。
Dalton Trans. 2013 Aug 14;42(30):10694-706. doi: 10.1039/c3dt50496d. Epub 2013 Apr 29.
9
Solvent-Induced and Temperature-Promoted Aggregation of Bipyridine Platinum(II) Triangular Metallacycles and Their Near-Infrared Emissive Behaviors.溶剂诱导和温度促进的联吡啶铂(II)三角金属环的聚集及其近红外发光行为。
Chemistry. 2018 Aug 9;24(45):11611-11618. doi: 10.1002/chem.201802499. Epub 2018 Jul 31.
10
Near-infrared-emitting heteroleptic cationic iridium complexes derived from 2,3-diphenylbenzo[g]quinoxaline as in vitro theranostic photodynamic therapy agents.基于 2,3-二苯基苯并[g]喹喔啉的近红外发射杂环阳离子铱配合物作为体外诊断与治疗的光动力治疗试剂。
Dalton Trans. 2017 Jun 27;46(25):8091-8103. doi: 10.1039/c7dt00913e.