Chemistry Department, M.V. Lomonosov Moscow State University, Leninskye Gory 1, 3, Moscow 119991, Russia.
A.V. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, Leninsky Pr. 29, Moscow 119991, Russia.
Int J Mol Sci. 2023 Sep 1;24(17):13575. doi: 10.3390/ijms241713575.
The aim of this work was to understand the main structural features and ways of formation of Ge-O bonds in organogermanium compounds under the conditions of ArGeHal (Hal = halide) hydrolysis. The structural types of these compounds were considered, providing 11 blocks (-). The molecular structures of the novel compounds [(-FCH)Ge]O (), [(-FCCH)Ge]O (), and -[(-FCCH)GeO] () were studied through XRD (X-ray diffraction) analysis. The molecular structure of [(-FCCH)GeO]Ge (), representing a novel structural type, was also investigated. The data presented in this study will be important in the design of materials with useful properties based on group 14 element derivatives with element-oxygen bonding.
这项工作的目的是在 ArGeHal（Hal = 卤化物）水解的条件下，了解有机锗化合物中 Ge-O 键的主要结构特征和形成方式。考虑了这些化合物的结构类型，提供了 11 个块（-）。通过 XRD（X 射线衍射）分析研究了新型化合物 [(-FCH)Ge]O ()、[(-FCCH)Ge]O ()和 -[(-FCCH)GeO] ()的分子结构。还研究了代表新型结构类型的 [(-FCCH)GeO]Ge ()的分子结构。本研究提供的数据对于设计具有有用性质的基于 14 族元素衍生物与元素-氧键的材料将是重要的。
