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过渡金属二硫属化物纳米卷轴:制备与应用

Transition Metal Dichalcogenides Nanoscrolls: Preparation and Applications.

作者信息

Yu Shilong, Wang Pinyi, Ye Huihui, Tang Hailun, Wang Siyuan, Wu Zhikang, Pei Chengjie, Lu Junhui, Li Hai

机构信息

Key Laboratory of Flexible Electronics (KLOFE) & Institute of Advanced Materials (IAM), Nanjing Tech University, Nanjing 211816, China.

出版信息

Nanomaterials (Basel). 2023 Aug 27;13(17):2433. doi: 10.3390/nano13172433.

DOI:10.3390/nano13172433
PMID:37686941
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC10490124/
Abstract

Two-dimensional (2D) transition metal dichalcogenides (TMDCs) nanosheets have shown extensive applications due to their excellent physical and chemical properties. However, the low light absorption efficiency limits their application in optoelectronics. By rolling up 2D TMDCs nanosheets, the one-dimensional (1D) TMDCs nanoscrolls are formed with spiral tubular structure, tunable interlayer spacing, and opening ends. Due to the increased thickness of the scroll structure, the light absorption is enhanced. Meanwhile, the rapid electron transportation is confined along the 1D structure. Therefore, the TMDCs nanoscrolls show improved optoelectronic performance compared to 2D nanosheets. In addition, the high specific surface area and active edge site from the bending strain of the basal plane make them promising materials for catalytic reaction. Thus, the TMDCs nanoscrolls have attracted intensive attention in recent years. In this review, the structure of TMDCs nanoscrolls is first demonstrated and followed by various preparation methods of the TMDCs nanoscrolls. Afterwards, the applications of TMDCs nanoscrolls in the fields of photodetection, hydrogen evolution reaction, and gas sensing are discussed.

摘要

二维(2D)过渡金属二硫属化物(TMDCs)纳米片因其优异的物理和化学性质而展现出广泛的应用。然而,低光吸收效率限制了它们在光电子学中的应用。通过将二维TMDCs纳米片卷曲起来,一维(1D)TMDCs纳米卷轴得以形成,其具有螺旋管状结构、可调的层间距和开口端。由于卷轴结构厚度的增加,光吸收得以增强。同时,快速的电子传输被限制在一维结构中。因此,与二维纳米片相比,TMDCs纳米卷轴展现出了改善的光电子性能。此外,高比表面积以及由基面弯曲应变产生的活性边缘位点使它们成为催化反应的有前景的材料。因此,TMDCs纳米卷轴近年来受到了广泛关注。在这篇综述中,首先阐述了TMDCs纳米卷轴的结构,随后介绍了TMDCs纳米卷轴的各种制备方法。之后,讨论了TMDCs纳米卷轴在光探测、析氢反应和气体传感领域的应用。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2303/10490124/194ec594db9d/nanomaterials-13-02433-g015.jpg
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https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2303/10490124/fea833a58dca/nanomaterials-13-02433-g010.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2303/10490124/9fa727725050/nanomaterials-13-02433-g011.jpg
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https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2303/10490124/a7c3b604887f/nanomaterials-13-02433-g013.jpg
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https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2303/10490124/83c5da402080/nanomaterials-13-02433-g002.jpg
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https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2303/10490124/9082713e16df/nanomaterials-13-02433-g004.jpg
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https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2303/10490124/9aa2bb9ba4c3/nanomaterials-13-02433-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2303/10490124/0f4a8fc5b586/nanomaterials-13-02433-g007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2303/10490124/f9870c08973a/nanomaterials-13-02433-g008.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2303/10490124/3327d8a5598f/nanomaterials-13-02433-g009.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2303/10490124/fea833a58dca/nanomaterials-13-02433-g010.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2303/10490124/9fa727725050/nanomaterials-13-02433-g011.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2303/10490124/080fc753e5ad/nanomaterials-13-02433-g012.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2303/10490124/a7c3b604887f/nanomaterials-13-02433-g013.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2303/10490124/26ed2157873b/nanomaterials-13-02433-g014.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2303/10490124/194ec594db9d/nanomaterials-13-02433-g015.jpg

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