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粒化高炉矿渣(GGBS)和碱性转炉钢渣(ACBFS)在90天时在刚性混凝土路面应用中的潜在作用。

Potential Role of GGBS and ACBFS Blast Furnace Slag at 90 Days for Application in Rigid Concrete Pavements.

作者信息

Nicula Liliana Maria, Manea Daniela Lucia, Simedru Dorina, Cadar Oana, Dragomir Mihai Liviu, Ardelean Ioan, Corbu Ofelia

机构信息

Faculty of Civil Engineering, Technical University of Cluj-Napoca, 28, Memorandumului, 400114 Cluj-Napoca, Romania.

Faculty of Construction, Cadastre and Architecture, University of Oradea, 4, B.S. Delavrancea Street, 410058 Oradea, Romania.

出版信息

Materials (Basel). 2023 Aug 29;16(17):5902. doi: 10.3390/ma16175902.

Abstract

Incorporating blast furnace slag into the composition of paving concrete can be one of the cost-effective ways to completely eliminate by-products from the pig iron production process (approximately 70% granulated slag and 30% air-cooled slag). The possibility to reintroduce blast furnace slag back into the life cycle will provide significant support to current environmental concerns and the clearance of tailings landfills. Especially in recent years, granulated and ground blast furnace slag (GGBS) as a substitute for cement and air-cooled blast furnace slag (ACBFS) aggregates as a substitute for natural aggregates in the composition of concretes have been studied by many researchers. But concrete compositions with large amounts of incorporated blast furnace slag affect the mechanical and durability properties through the interaction between the slag, cement and water depending on the curing times. This study focuses on identifying the optimal proportions of GGBS as a supplementary cementitious material (SCM) and ACBFS aggregates as a substitute to natural sand such that the performance at 90 days of curing the concrete is similar to that of the control concrete. In addition, to minimize the costs associated with grinding GGBS, the hydration activity index (HAI) of the GGBS, the surface morphology, and the mineral components were analyzed via X-ray diffraction, scanning electron microscopy (SEM), energy dispersive spectrometry (EDX), and nuclear magnetic resonance relaxometry (NMR). The flexural strength, the basic mechanical property of road concretes, increased from 28 to 90 days by 20.72% and 20.26% for the slag concrete but by 18.58% for the reference concrete. The composite with 15% GGBS and 25% ACBFS achieved results similar to the reference concrete at 90 days; therefore, they are considered optimal percentages to replace cement and natural sand in ecological pavement concretes. The HAI of the slag powder with a specific surface area equivalent to that of Portland cement fell into strength class 80 at the age of 28 days, but at the age of 90 days, the strength class was 100. The results of this research present three important benefits: the first is the protection of the environment through the recycling of two steel industry wastes that complies with European circular economy regulations, and the second is linked to the consequent savings in the disposal costs associated with wastefully occupied warehouses and the savings in slag grinding.

摘要

将高炉矿渣掺入路面混凝土成分中,可能是彻底消除生铁生产过程中副产品(约70%的粒化矿渣和30%的风冷矿渣)的一种经济有效的方法。将高炉矿渣重新引入生命周期的可能性,将为当前的环境问题和尾矿填埋场的清理提供有力支持。特别是近年来,许多研究人员对粒化高炉矿渣(GGBS)作为水泥替代品以及风冷高炉矿渣(ACBFS)骨料作为混凝土成分中天然骨料替代品进行了研究。但是,大量掺入高炉矿渣的混凝土成分,会根据养护时间,通过矿渣、水泥和水之间的相互作用,影响其力学性能和耐久性。本研究的重点是确定GGBS作为辅助胶凝材料(SCM)和ACBFS骨料作为天然砂替代品的最佳比例,以使混凝土养护90天时的性能与对照混凝土相似。此外,为了尽量减少与粉磨GGBS相关的成本,通过X射线衍射、扫描电子显微镜(SEM)、能谱仪(EDX)和核磁共振弛豫测量(NMR)对GGBS的水化活性指数(HAI)、表面形态和矿物成分进行了分析。对于矿渣混凝土,作为道路混凝土基本力学性能的抗弯强度从28天到90天提高了20.72%和20.26%,而对照混凝土提高了18.58%。含15%GGBS和25%ACBFS的复合材料在90天时取得了与对照混凝土相似的结果;因此,它们被认为是生态路面混凝土中替代水泥和天然砂的最佳比例。比表面积与波特兰水泥相当的矿渣粉的HAI在28天时属于强度等级80,但在90天时强度等级为100。本研究结果带来了三个重要益处:一是通过回收两种符合欧洲循环经济法规的钢铁工业废料来保护环境,二是由此节省了与占用大量仓库相关的处置成本以及矿渣粉磨成本。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d464/10488527/b84930f3b6d5/materials-16-05902-g001.jpg

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