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细度对粒化高炉矿渣粉水化活性指数的影响

The Effect of Fineness on the Hydration Activity Index of Ground Granulated Blast Furnace Slag.

作者信息

Dai Jinpeng, Wang Qicai, Xie Chao, Xue Yanjin, Duan Yun, Cui Xiaoning

机构信息

National and Provincial Joint Engineering Laboratory of Road & Bridge Disaster Prevention and Control, Lanzhou Jiaotong University, Lanzhou 730070, China.

Civil Engineering Department, Lanzhou Jiaotong University, Lanzhou 730070, China.

出版信息

Materials (Basel). 2019 Sep 15;12(18):2984. doi: 10.3390/ma12182984.

Abstract

To improve the properties of ground granulated blast furnace slag (GGBS) and utilize ground granulated blast furnace slag efficiently, this study investigates the effect of fineness on the hydration activity index (HAI) of ground granulated blast furnace slag. The hydration activity index of GGBS with six specific surface areas (SSAs) was characterized by the ratio of compressive strength of the prismatic mortar test block. The particle size distribution of GGBS with different grinding times was tested by laser particle size analyzer. The paste of different specific surface area GGBSs in different curing ages was investigated at the micro level by X-ray diffraction, scanning electron microscope, energy dispersive spectrometer, thermogravimetric scanning calorimeter, and differential scanning calorimeter. The effect of particle distribution of GGBS on the hydration activity index of different curing ages was studied by gray correlation analysis. The results indicated that the compressive strength and hydration activity index increases with the increase of a specific surface area of GGBS at different curing ages. The hydration activity index at different curing ages is almost a linear role for specific surface areas. With the increase in the specific surface area of GGBS, the content of Ca(OH) in paste decreases gradually. When GGBS was added into a mortar test block, the hydrate calcium silicate gel in paste changed from a high Ca/Si ratio to a low Ca/Si ratio. The 0-10 micron particles of GGBS particle distribution were highly correlated with the hydration activity index at different curing ages.

摘要

为改善粒化高炉矿渣(GGBS)性能并高效利用粒化高炉矿渣,本研究探讨了细度对粒化高炉矿渣水化活性指数(HAI)的影响。通过棱柱形砂浆试块抗压强度比来表征具有六种比表面积(SSA)的GGBS的水化活性指数。用激光粒度分析仪测试不同粉磨时间的GGBS的粒度分布。利用X射线衍射、扫描电子显微镜、能谱仪、热重扫描量热仪和差示扫描量热仪,从微观层面研究不同比表面积GGBS在不同养护龄期的浆体。通过灰色关联分析研究GGBS颗粒分布对不同养护龄期水化活性指数的影响。结果表明,在不同养护龄期,GGBS的抗压强度和水化活性指数随比表面积的增加而增大。不同养护龄期的水化活性指数对比表面积几乎呈线性关系。随着GGBS比表面积的增加,浆体中Ca(OH)含量逐渐降低。当GGBS加入到砂浆试块中时,浆体中水化硅酸钙凝胶的Ca/Si比从高变低。GGBS颗粒分布中0 - 10微米的颗粒与不同养护龄期的水化活性指数高度相关。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/704f/6766355/59a3f000ba6c/materials-12-02984-g001.jpg

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