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基于海藻酸钠包裹多壁碳纳米管与二硫化钼复合电极膜的仿生人工肌肉

Bioinspired Artificial Muscles Based on Sodium Alginate-Wrapped Multi-Walled Carbon Nanotubes and Molybdenum Disulfide Composite Electrode Membrane.

作者信息

Ji Yingxin, Wang Keyi, Zhao Gang

机构信息

College of Mechanical and Electrical Engineering, Harbin Engineering University, Harbin 150001, China.

出版信息

Polymers (Basel). 2023 Aug 25;15(17):3535. doi: 10.3390/polym15173535.

Abstract

Using a naturally extracted polymer sodium alginate extracted from natural seaweed as the primary raw material, we have successfully developed an electroactive actuator known as biomimetic artificial muscle (BMAM). In comparison to conventional synthetic materials, this BMAM aligns more coherently with the prevailing principles of environmentally friendly development. During the preparation of the BMAM electrode membrane, we employed ultrasonic oscillation to adsorb varying quantities of MoS onto a reticulated structure formed by multi-walled carbon nanotubes (MWCNTs), thus enhancing the mechanical and electrochemical performance of the BMAM. Scanning electron microscopy and energy-dispersive X-ray spectroscopy (EDS) confirmed the successful encapsulation of MoS by the MWCNTs network in the composite. To measure the output force of the BMAM fabricated with different masses of MoS doping, we established a self-built experimental platform and conducted tests on the electrode membranes doped with varying quantities of MoS using an electrochemical workstation. The results revealed that the BMAM exhibited optimal mechanical performance when doped with 1.5 g of MoS, with a maximum output force of 7.81 mN, an output force density of 34.36 mN/g, and a response rate of 0.09 mN/s. These performances were improved by 309%, 276%, and 175%, respectively, compared to the samples without MoS doping, with a mass-specific capacitance enhancement of 151%.

摘要

我们以从天然海藻中提取的天然聚合物海藻酸钠为主要原料,成功开发了一种名为仿生人工肌肉(BMAM)的电活性致动器。与传统合成材料相比,这种BMAM更符合当前环境友好型发展的原则。在制备BMAM电极膜的过程中,我们采用超声振荡将不同量的MoS吸附到由多壁碳纳米管(MWCNT)形成的网状结构上,从而提高了BMAM的机械和电化学性能。扫描电子显微镜和能量色散X射线光谱(EDS)证实了复合材料中MWCNT网络成功包裹了MoS。为了测量不同质量MoS掺杂制备的BMAM的输出力,我们搭建了一个自建实验平台,并使用电化学工作站对掺杂不同量MoS的电极膜进行测试。结果表明,当掺杂1.5 g MoS时,BMAM表现出最佳机械性能,最大输出力为7.81 mN,输出力密度为34.36 mN/g,响应速率为0.09 mN/s。与未掺杂MoS的样品相比,这些性能分别提高了309%、276%和175%,质量比电容提高了151%。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4bdb/10490135/289a0ff2dfed/polymers-15-03535-g001.jpg

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