Anish M C, Pandey Krishna K, Kumar Rakesh
Institute of Wood Science and Technology, Bengaluru, Karnataka, India.
Department of Forest Products and Utilization, College of Forestry, Kerala Agricultural University, Thrissur, Kerala, India.
Sci Rep. 2023 Sep 9;13(1):14915. doi: 10.1038/s41598-023-42242-7.
Transparent wood (TW) has garnered significant global attention due to its unique properties. In this study, TW composites were fabricated using two timber species of different density classes: Ailanthus triphysa (common name: Ailanthus wood) and Hevea brasiliensis (common name: Rubberwood). Sodium hydroxide (NaOH) and Hydrogen peroxide-based alkali method was used to modify the lignin in these veneer samples, producing a white cellulose template with a fully intact hierarchical cell structure. Subsequently, a cost-effective thermosetting unsaturated polyester resin (UPR) was infiltrated into the redesigned framework and polymerized to create rigid nanostructured transparent composites. High optical haze (of 94% and 89%) and favourable light transmittance of 59 and 55 percent were exhibited by the UPR-TW composites made from rubberwood and ailanthus wood, respectively. TW was characterised using Scanning electron microscopy and Fourier-transform infrared spectroscopy. The mechanical properties of TW were measured and compared with those of natural wood and pure-polymer. Furthermore, the anisotropic light diffusion behaviour displayed by TW in accordance with the fibre orientation indicates the utility of material as a potential light shaping device. Therefore, a cost-effective and commercially viable strategy to fabricate multipurpose TW composites using a combination of lesser-known timber species (LKTS) and UPR resin was successfully demonstrated.
透明木材(TW)因其独特性能而在全球引起了广泛关注。在本研究中,使用两种不同密度等级的木材制备了TW复合材料:臭椿(俗名:臭椿木)和巴西橡胶树(俗名:橡胶木)。采用氢氧化钠(NaOH)和基于过氧化氢的碱法对这些单板样品中的木质素进行改性,制备出具有完整分级细胞结构的白色纤维素模板。随后,将一种经济高效的热固性不饱和聚酯树脂(UPR)渗入重新设计的框架中并聚合,以制造出刚性纳米结构透明复合材料。由橡胶木和臭椿木制成的UPR-TW复合材料分别具有94%和89%的高光学雾度以及59%和55%的良好透光率。使用扫描电子显微镜和傅里叶变换红外光谱对TW进行了表征。测量了TW的力学性能,并与天然木材和纯聚合物的力学性能进行了比较。此外,TW根据纤维取向表现出的各向异性光扩散行为表明该材料可作为一种潜在的光整形器件。因此,成功展示了一种使用鲜为人知的木材种类(LKTS)和UPR树脂组合制备多功能TW复合材料的经济高效且具有商业可行性的策略。