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全生物基透明木材:一种新方法及其环保包装应用。

All-biobased transparent-wood: A new approach and its environmental-friendly packaging application.

机构信息

CRC for Nanocellulose Future Composites, Inha University, Incheon, 22212, Republic of Korea; Pulp and Paper Technology Dept., Phutho College of Industry and Trade, Phutho, Viet Nam.

CRC for Nanocellulose Future Composites, Inha University, Incheon, 22212, Republic of Korea.

出版信息

Carbohydr Polym. 2021 Jul 15;264:118012. doi: 10.1016/j.carbpol.2021.118012. Epub 2021 Apr 2.

Abstract

Transparent-wood (TW) is an emerging research topic that can be applied to biobased products. However, it is necessary to fill pores in TW with natural substances to prepare all-biobased TW. This paper reports an all-biobased TW by infiltrating cellulose nanofiber (CNF) and chitosan (CTS) suspensions into the bleached wood. CNF was isolated by combining the chemical and physical methods, and CTS was dissolved in acetic acid, and they were infiltrated into the pores of the bleached Fir veneer wood using a vacuum jar. The CNF and chitosan effects on the mechanical properties of the TW were studied, and the morphologies, crystallinity index, water contact angle, antioxidant, thermal degradation, and UV-shielding properties were investigated. The prepared TW showed 80 % total transmittance and 30-60 % haze, suitable for solar cell application. The all-biobased TW showed good thermal stability up to 315 °C and excellent UV shielding property for UV-B and UV-C. The antioxidant property of the CTS-TW significantly increased as compared to the original wood. The CNF-TW showed considerable tensile strength and yield strength of more than 200 % improved from the original wood. The potential for environment-friendly packaging applications was demonstrated by making a bag, medicine packaging, and straw for a drink.

摘要

透明木材(TW)是一个新兴的研究课题,可应用于生物基产品。然而,有必要用天然物质填充 TW 的孔隙,以制备全生物基 TW。本文通过将纤维素纳米纤维(CNF)和壳聚糖(CTS)悬浮液渗透到漂白木材中,报道了一种全生物基 TW。CNF 通过结合化学和物理方法分离,CTS 溶解在乙酸中,然后用真空罐将它们渗透到漂白的冷杉单板木材的孔隙中。研究了 CNF 和壳聚糖对 TW 力学性能的影响,并研究了 TW 的形态、结晶度指数、水接触角、抗氧化、热降解和紫外线屏蔽性能。所制备的 TW 表现出 80%的总透光率和 30-60%的雾度,适合用于太阳能电池。全生物基 TW 表现出良好的热稳定性,高达 315°C,对 UV-B 和 UV-C 具有优异的紫外线屏蔽性能。与原木材相比,壳聚糖 TW 的抗氧化性能显著提高。与原木材相比,CNF-TW 表现出相当大的拉伸强度和屈服强度,提高了 200%以上。通过制作袋子、药品包装和饮料吸管,展示了其在环保包装应用方面的潜力。

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