Zhao Lei, Xie Longfei, Gou Le, Dai Liyi, Wang Yuanyuan
Shanghai Key Laboratory of Green Chemistry and Chemical Processes, School of Chemistry and Molecular Engineering, East China Normal University Shanghai 200062 China
State Key Laboratory of Petroleum Molecular and Process Engineering, SKLPMPE, Sinopec Research Institute of Petroleum Processing Co., LTD. Beijing 100083 China.
RSC Adv. 2023 Sep 11;13(39):27116-27124. doi: 10.1039/d3ra03809b. eCollection 2023 Sep 8.
Sewage sludge (SS), a hazardous solid waste with a high water and pollutant content, should be disposed of correctly. Hydrothermal liquefaction (HTL) shows tremendous potential to treat organic matter with substantial water content like SS. In this paper, we examined the impact of key factors on the characteristics and yield of bio-oil during HTL of SS. We clarified the impacts of each component on the yield through model compounds based on that and constructed a component additivity model for forecasting the bio-oil yield from biomass with complex component composition. In the reactions of the model compounds, cellulose showed synergistic interaction with protein and alkali lignin in the bio-oil yield but lipids showed antagonistic effects with protein and alkaline lignin. The co-HTL results of these binary mixtures improved our model and further clarified the reaction mechanism of HTL of SS.
污水污泥(SS)是一种含水量和污染物含量高的危险固体废物,应正确处置。水热液化(HTL)在处理像SS这样含水量高的有机物质方面显示出巨大潜力。在本文中,我们研究了关键因素对SS水热液化过程中生物油特性和产率的影响。在此基础上,通过模型化合物阐明了各组分对产率的影响,并构建了一个组分加和模型,用于预测具有复杂组分组成的生物质的生物油产率。在模型化合物的反应中,纤维素在生物油产率方面与蛋白质和碱木质素表现出协同作用,而脂质与蛋白质和碱性木质素表现出拮抗作用。这些二元混合物的共水热液化结果改进了我们的模型,并进一步阐明了SS水热液化的反应机理。