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仿蝉翼透明聚苯乙烯薄膜集自清洁、防雾和抗菌性能于一体。

Cicada Wing-Inspired Transparent Polystyrene Film Integrating Self-Cleaning, Antifogging, and Antibacterial Properties.

机构信息

Key Laboratory of Material Chemistry for Energy Conversion and Storage, Ministry of Education, Hubei Key Laboratory of Material Chemistry and Service Failure and Hubei Engineering Research Center for Biomaterials and Medical Protective Materials, School of Chemistry and Chemical Engineering, Huazhong University of Science and Technology, Wuhan 430074, Hubei, China.

Kingfa Science and Technology Co., LTD., Guangzhou 510663, Guangdong, China.

出版信息

ACS Appl Mater Interfaces. 2023 Oct 4;15(39):46538-46549. doi: 10.1021/acsami.3c10214. Epub 2023 Sep 20.

Abstract

A transparent film integrating antifouling, antifogging, and antibacterial properties is crucial for its application as a protective mask, goggles, or lens. Herein, applying dynamic injection molding coupled with a bionic gradient template, a fast and efficient method is proposed for the preparation of the bionic polystyrene surface (BNPPS) with a cicada wing-inspired nanopillar structure. The contact angle of the BNPPS film increases continuously along the wing vein, while the sliding angle decreases continuously, mimicking the gradient wetting state of a cicada wing and providing excellent self-propelled removal properties for tiny water droplets. Notably, the BNPPS film has a transmittance higher than 90% and a reflectivity lower than 5% in the visible light range. Dyeing water, milk, juice, cola, and ink can slide smoothly from the BNPPS film surface without leaving any residue. Importantly, the nanopillars on the BNPPS film surface can penetrate and kill most of the within 20 min. Therefore, the prepared BNPPS film with sufficient mechanical strength gathers the unique properties of the cicada wing together. The proposed research is expected to offer valuable guidance for fabricating self-cleaning, antifogging, and antibacterial optical devices that could be utilized in medical and vision systems operating in harsh environments.

摘要

一种集防污、防雾和抗菌性能于一体的透明薄膜对于将其用作防护口罩、护目镜或镜片至关重要。在此,通过应用动态注塑和仿生梯度模板,提出了一种快速高效的方法来制备具有仿蝉翼纳米柱结构的仿生聚苯乙烯表面(BNPPS)。BNPPS 薄膜的接触角沿着翼脉连续增加,而滑动角连续减小,模拟了蝉翼的梯度润湿状态,为微小水滴提供了出色的自推进去除性能。值得注意的是,BNPPS 薄膜在可见光范围内的透光率高于 90%,反射率低于 5%。染色水、牛奶、果汁、可乐和墨水可以从 BNPPS 薄膜表面顺利滑落,不会留下任何残留物。重要的是,BNPPS 薄膜表面的纳米柱可以穿透并杀死大部分,在 20 分钟内。因此,所制备的具有足够机械强度的 BNPPS 薄膜汇集了蝉翼的独特特性。这项研究有望为制造自清洁、防雾和抗菌的光学器件提供有价值的指导,这些光学器件可用于在恶劣环境中运行的医疗和视觉系统。

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