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受生物启发的聚亚乙基亚胺和单宁酸复合物的粘附涂层,具有防雾、自清洁和抗菌能力。

Bioinspired adhesive coatings from polyethylenimine and tannic acid complexes exhibiting antifogging, self-cleaning, and antibacterial capabilities.

机构信息

Hubei Engineering Research Center for Biomaterials and Medical Protective Materials, School of Chemistry & Chemical Engineering, Huazhong University of Science and Technology (HUST), Wuhan 430074, China.

Hubei Engineering Research Center for Biomaterials and Medical Protective Materials, School of Chemistry & Chemical Engineering, Huazhong University of Science and Technology (HUST), Wuhan 430074, China.

出版信息

J Colloid Interface Sci. 2021 Nov 15;602:406-414. doi: 10.1016/j.jcis.2021.06.032. Epub 2021 Jun 9.

Abstract

In this work, we develop a simple yet robust method to fabricate a bioinspired adhesive coating based on polyethyleneimine (PEI) and tannic acid (TA) complexes, exhibiting excellent antifogging, self-cleaning, and antibacterial properties. The polyethyleneimine-tannic acid (PEI-TA) complexes coating combined with the bioinspired adhesive property from TA can be effectively and stably coated onto various substrates through a one-step deposition process, and the hydrophilicity of the coated substrates can be significantly enhanced with their water contact angle less than 10°. The bioinspired adhesive coating endows the coated substrates with outstanding antifogging and self-cleaning performance. Moreover, it is found that the PEI-TA coated safety goggles display excellent durability and antifogging capability compared to the commercial antifogging safety goggles and commercial antifogging agents coated safety goggles under 65 ℃ vapor condition for 2 h. Furthermore, the PEI-TA coatings show superior antibacterial activities for Gram-negative Escherichiak coli and Gram-positive Staphylococcus aureus. The antifogging, self-cleaning, and antibacterial coating provides widely potential application prospects in optical and medical devices.

摘要

在这项工作中,我们开发了一种简单而强大的方法,基于聚乙烯亚胺(PEI)和单宁酸(TA)复合物来制造仿生粘附涂层,该涂层具有出色的防雾、自清洁和抗菌性能。聚乙烯亚胺-单宁酸(PEI-TA)复合物涂层结合了 TA 的仿生粘附特性,可以通过一步沉积过程有效地稳定地涂覆到各种基底上,并且涂层基底的亲水性可以显著增强,其水接触角小于 10°。仿生粘附涂层赋予了涂层基底出色的防雾和自清洁性能。此外,与商业防雾安全眼镜和涂有商业防雾剂的安全眼镜相比,PEI-TA 涂层的安全眼镜在 65℃蒸汽条件下 2 小时后,显示出卓越的耐用性和防雾性能。此外,PEI-TA 涂层对革兰氏阴性大肠杆菌和革兰氏阳性金黄色葡萄球菌具有优异的抗菌活性。防雾、自清洁和抗菌涂层为光学和医疗设备提供了广泛的潜在应用前景。

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