Zheng Yan, Teng Bing-Hong, Zhang Youcan, Wu Xiao-Feng
Dalian National Laboratory for Clean Energy, Dalian Institute of Chemical Physics, Chinese, Academy of Sciences, 116023, Dalian, Liaoning, China.
School of Chemistry and Chemical Engineering, Liaoning Normal University, 850 Huanghe Road, Dalian, 116029, China.
Chem Asian J. 2023 Nov 2;18(21):e202300766. doi: 10.1002/asia.202300766. Epub 2023 Oct 5.
In this work, we developed a photo-induced carbonylation of aryl bromides under transition metal-free conditions. The reaction shows good activity with alcohol and amine nucleophiles. Various esters and amides were formed from aryl halides and alcohols and amines under mild conditions in moderate to good yields.
在这项工作中，我们开发了一种在无过渡金属条件下芳基溴的光诱导羰基化反应。该反应对醇类和胺类亲核试剂表现出良好的活性。在温和条件下，芳基卤化物与醇类和胺类反应生成了各种酯类和酰胺类化合物，产率适中至良好。
