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基于HS-SPME-GC-MS联用技术的七种植物挥发性化合物分析及化学计量学分类研究

Volatile Compound Profiling of Seven Species Using HS-SPME-GC-MS and Classification by a Chemometric Approach.

作者信息

Korkmaz Cansu, Hellal Khaoula, Taş Küçükaydın Meltem, Çayan Fatih, Küçükaydın Selçuk, Duru Mehmet Emin

机构信息

Department of Biology, Faculty of Science, Muğla Sıtkı Koçman University, 48000 Muğla, Turkey.

Department of Chemistry, Faculty of Science, Muğla Sıtkı Koçman University, 48000 Muğla, Turkey.

出版信息

ACS Omega. 2023 Sep 5;8(37):34111-34119. doi: 10.1021/acsomega.3c05292. eCollection 2023 Sep 19.

DOI:10.1021/acsomega.3c05292
PMID:37744840
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC10515357/
Abstract

Edible mushrooms are important providers of nutrients and are well recognized for their particular organoleptic properties. The volatiles that releases serve purposes beyond simply appealing to our sense of smell. Truffles have different smells and tastes due to the fact that they contain different volatile components; therefore, aroma is essential in defining the organoleptic properties and quality of truffles. In this research, seven species, namely, , , , , , , and were selected. The primary objective of this study was to carry out the first in-depth investigation of the volatile compounds and chemometric analysis of seven truffle species from the genus that are grown in Turkey. The SPME headspace combined with GC-MS analysis identified 60 volatiles from different classes, with the abundance of terpenes being followed in a decreasing order by alcohols, aldehydes, sulfides, ketones, and other aromatic compounds. According to the chemometric analysis, methional, 3-methyl-4,5-dihydrothiophene, -(methylthio) benzaldehyde, 3-octene, linalyl acetate, methyl caproate, and β-trans-ocimene could be highlighted as markers for grown in Turkey. This investigation was conducted for the first time using , , and . The comparison of the volatile profile of these tubers' species displayed branded differences. Thus, the knowledge gained from this research may pave the way to identify the key aroma contributors in the chosen species.

摘要

可食用蘑菇是重要的营养提供者,并因其独特的感官特性而广为人知。所释放的挥发性物质不仅能吸引我们的嗅觉。松露由于含有不同的挥发性成分而具有不同的气味和味道;因此,香气对于定义松露的感官特性和品质至关重要。在本研究中,选择了七个物种,即,,,,,,和。本研究的主要目的是对在土耳其种植的来自属的七种松露的挥发性化合物进行首次深入研究并进行化学计量分析。固相微萃取顶空结合气相色谱 - 质谱分析鉴定出60种不同类别的挥发性物质,萜类的丰度之后依次是醇类、醛类、硫化物、酮类和其他芳香化合物。根据化学计量分析,甲硫醛、3 - 甲基 - 4,5 - 二氢噻吩、 - (甲硫基)苯甲醛、3 - 辛烯、乙酸芳樟酯、己酸甲酯和β - 反式罗勒烯可被视为在土耳其种植的的标志物。本研究首次使用,,和进行。这些块茎物种挥发性成分的比较显示出显著差异。因此,从本研究中获得的知识可能为确定所选物种中的关键香气成分铺平道路。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d97f/10515357/5cfd5cba80b7/ao3c05292_0003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d97f/10515357/c4df1cdde9a0/ao3c05292_0002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d97f/10515357/5cfd5cba80b7/ao3c05292_0003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d97f/10515357/c4df1cdde9a0/ao3c05292_0002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d97f/10515357/5cfd5cba80b7/ao3c05292_0003.jpg

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