N-杂环亚胺催化的1,4-区域选择性叠氮化物-炔烃环加成反应（AAC）：一种无金属方法。
N-Heterocyclic imino-catalyzed 1,4-regioselective azide-alkyne cycloaddition (AAC): a metal-free approach.
作者信息
Revathi Shanmugam, Shinde Aditya L, Rajashekhar Mulimani K, Mandal Debasish, Maity Amit Ranjan, Garai Somenath, Ghatak Tapas
机构信息
Advanced Catalysis Facility, Department of Chemistry, School of Advanced Sciences, Vellore Institute of Technology, Vellore-632014, Tamil Nadu, India.
Thapar Institute of Engineering and Technology, Punjab, India.
出版信息
Chem Commun (Camb). 2023 Oct 24;59(85):12699-12702. doi: 10.1039/d3cc04065h.
An unprecedented synthetic approach has been devised to efficiently synthesize regioselective 1,4-disubstituted 1,2,3-triazoles. This technique relies on the use of innovative metal-free highly basic N-heterocyclic imino catalysts. The experimental observations have been supported further by TD-DFT computational studies.
已经设计出一种前所未有的合成方法来高效合成区域选择性1,4-二取代的1,2,3-三唑。该技术依赖于使用创新的无金属高碱性N-杂环亚氨基催化剂。TD-DFT计算研究进一步支持了实验观察结果。
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