Three-Dimensional Polypyrrole-Decorated CuCoS Nanowires Anchored on Nickel Foam: A Promising Electrode for High-Performance Supercapacitors.

The exploitation of high-performance supercapacitors is crucial to promote energy storage technologies. Benefiting from the three-dimensional conductive micronanostructures and high specific capacity of the PPy@CuCoS@NF (polypyrrole/copper cobalt sulfide/nickel foam) composite electrode, this electrode exhibits a high specific capacity of 1403.21 C g at 1 A g and a capacitance retention of 85.79% after 10,000 cycles at 10 A g. The assembled PPy@CuCoS@NF//AC aqueous hybrid supercapacitor (AHSC) reveals a wide operating potential window of 1.5 V and achieves a high specific capacity of 322.52 C g at 1 A g and a capacitance retention of 86.84% after 15,000 cycles at 10 A g. The AHSC also exhibits a high power density of 733.69 W kg at an energy density of 67.19 W h kg, surpassing those of previously reported spinel-based supercapacitors. Ex situ X-ray diffraction and X-ray photoelectron spectroscopy results show that the CuCoS spinel structure changes to CuS and CoS cube structures, and the oxidation states of Cu and Co increase during charging and discharging processes. Density functional theory calculations suggest a superior conductivity for CuCoS compared to that for CuCoO, demonstrating that CuCoS has superior electrochemical performance. These findings attest to the considerable potential of the spinel materials for advanced energy storage applications.