Expanded Vermiculite/D-Mannitol as Shape-Stable Phase Change Material for Medium Temperature Heat Storage.

Aiming to promote the application of D-mannitol in the field of phase change thermal storage, obstacles, including low thermal storage efficiency and high supercooling, should be properly disposed of. The adoption of adaptable and low-cost supporting materials to make shape-stable phase change materials (ss-PCMs) affordable is a primary solution to solve the above shortcomings. In this study, high-performance ss-PCM for effective medium-temperature heat storage was prepared using expanded vermiculite as the support for D-mannitol preservation. Among the three candidates that treated the raw vermiculite by dilute acid, calcination, and microwave heating, the calcinated expanded vermiculite (CV) was characterized as the most suitable one. After impregnating D-mannitol into the CV carrier by vacuum, a melting enthalpy of 205.1 J/g and a crystallization enthalpy of 174.1 J/g were achieved by the as-received CV/D-mannitol ss-PCM. Additionally, the supercooling of the ss-PCM was reduced to 45.6 °C. The novel CV/D-mannitol ss-PCM also exhibited excellent reusability and stability. All the findings indicate that the abundant and inexpensive CV exhibited great potential as the supporting material for D-mannitol-based ss-PCMs, which allow effective waste heat recovery and temperature regulation.