• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利：CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法，用中文像聊天一样搜索，搜遍4000万医学文献。AI智能推荐，让科研检索更轻松。

立即免费搜索

文件翻译

保留排版，准确专业，支持PDF/Word/PPT等文件格式，支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述，25分钟生成高质量综述，智能提取关键信息，辅助科研写作。

立即免费体验

锌铝镁钢板强化表面疏松层的验证

Verification of Reinforced Surface Loose Layer of Zinc-Aluminum-Magnesium Steel Plate.

作者信息

Chen Junxue, Chen Zheng, Yang Junjiao

机构信息

College of Chemistry, Beijing University of Chemical Technology, Beijing 100029, China.

Analysis and Test Center, Beijing University of Chemical Technology, Beijing 100029, China.

出版信息

Materials (Basel). 2023 Sep 15;16(18):6221. doi: 10.3390/ma16186221.

DOI:10.3390/ma16186221
PMID:37763499
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC10533006/
Abstract

The corrosion resistance of zinc-aluminum-magnesium steel plates (Zn-Al-Mg steel plates) is significantly higher than that of galvanized steel plates. However, the unsatisfactory bonding performance of Zn-Al-Mg steel plates significantly limits their widespread application. In this study, X-ray photoelectron spectroscopy is employed to detect changes in the surface oxygen content of Zn-Al-Mg steel plates after different temperature treatments to confirm the existence of surface loose layers. In particular, changes in the surface oxygen content of the Zn-Al-Mg steel plates after the oxide layer is removed are investigated under saturated HO vapor and O environmental conditions, and the cause of the formation of loose surface layers is determined. The uneven distribution of elements on the surface of the Zn-Al-Mg steel plates is investigated with scanning electron microscopy and energy dispersive spectroscopy. Nuclear magnetic resonance is employed to determine the size of the network spatial structure formed by silane coupling agents under different hydrolysis conditions and to further investigate the bonding performance of hydrolysate-modified Zn-Al-Mg steel plates. Several typical automotive adhesives are utilized to compare and examine the changes in the tensile strength of the Zn-Al-Mg steel plate bonding before and after modification with the silane coupling agent and analyze the structural damage of the adhesive at the bonding interface. The results confirm that the silane coupling agent strengthens the loose layer on the surface of the Zn-Al-Mg steel plate.

摘要

锌铝镁钢板（Zn-Al-Mg钢板）的耐腐蚀性明显高于镀锌钢板。然而，Zn-Al-Mg钢板不尽人意的粘结性能显著限制了它们的广泛应用。在本研究中，采用X射线光电子能谱检测不同温度处理后Zn-Al-Mg钢板表面氧含量的变化，以确认表面疏松层的存在。特别地，研究了在饱和水蒸气和氧气环境条件下去除氧化层后Zn-Al-Mg钢板表面氧含量的变化，并确定了表面疏松层形成的原因。用扫描电子显微镜和能谱仪研究了Zn-Al-Mg钢板表面元素的不均匀分布。采用核磁共振确定不同水解条件下硅烷偶联剂形成的网络空间结构的尺寸，并进一步研究水解产物改性Zn-Al-Mg钢板的粘结性能。使用几种典型的汽车胶粘剂比较和检测用硅烷偶联剂改性前后Zn-Al-Mg钢板粘结的拉伸强度变化，并分析粘结界面处胶粘剂的结构损伤。结果证实，硅烷偶联剂强化了Zn-Al-Mg钢板表面的疏松层。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/fbc8/10533006/303b5852c8a1/materials-16-06221-g009.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/fbc8/10533006/290ea845f1f8/materials-16-06221-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/fbc8/10533006/88172d57f90a/materials-16-06221-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/fbc8/10533006/39a2b05d5e74/materials-16-06221-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/fbc8/10533006/f270abb1c130/materials-16-06221-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/fbc8/10533006/111b40c3c1d7/materials-16-06221-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/fbc8/10533006/917ba3ae98c9/materials-16-06221-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/fbc8/10533006/f9915e2fd5c1/materials-16-06221-g007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/fbc8/10533006/bc7a9bacdae3/materials-16-06221-g008.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/fbc8/10533006/303b5852c8a1/materials-16-06221-g009.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/fbc8/10533006/290ea845f1f8/materials-16-06221-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/fbc8/10533006/88172d57f90a/materials-16-06221-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/fbc8/10533006/39a2b05d5e74/materials-16-06221-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/fbc8/10533006/f270abb1c130/materials-16-06221-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/fbc8/10533006/111b40c3c1d7/materials-16-06221-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/fbc8/10533006/917ba3ae98c9/materials-16-06221-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/fbc8/10533006/f9915e2fd5c1/materials-16-06221-g007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/fbc8/10533006/bc7a9bacdae3/materials-16-06221-g008.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/fbc8/10533006/303b5852c8a1/materials-16-06221-g009.jpg

相似文献

1
Verification of Reinforced Surface Loose Layer of Zinc-Aluminum-Magnesium Steel Plate.锌铝镁钢板强化表面疏松层的验证
Materials (Basel). 2023 Sep 15;16(18):6221. doi: 10.3390/ma16186221.
2
Molecular Understanding of the Interfacial Interaction and Corrosion Resistance between Epoxy Adhesive and Metallic Oxides on Galvanized Steel.镀锌钢上环氧胶粘剂与金属氧化物之间界面相互作用和耐腐蚀性的分子理解
Materials (Basel). 2023 Apr 13;16(8):3061. doi: 10.3390/ma16083061.
3
Roles of Al and Mg on the Microstructure and Corrosion Resistance of Zn-Al-Mg Hot-Dipped Coated Steel.铝和镁对锌铝镁热浸镀层钢微观结构及耐蚀性的作用
Materials (Basel). 2024 Mar 27;17(7):1512. doi: 10.3390/ma17071512.
4
Effect of the Addition of Steel Fibers on the Bonding Interface and Tensile Properties of Explosion-Welded 2A12 Aluminum Alloy and SS-304 Steel.
Materials (Basel). 2022 Dec 22;16(1):116. doi: 10.3390/ma16010116.
5
Stress Concentration Analysis of the Corroded Steel Plate Strengthened with Carbon Fiber Reinforced Polymer (CFRP) Plates.碳纤维增强聚合物（CFRP）板加固锈蚀钢板的应力集中分析
Polymers (Basel). 2022 Sep 14;14(18):3845. doi: 10.3390/polym14183845.
6
Adhesion enhancement of steel fibers to acrylic bone cement through a silane coupling agent.通过硅烷偶联剂增强钢纤维与丙烯酸骨水泥的粘结力。
J Biomed Mater Res A. 2006 Jan;76(1):111-9. doi: 10.1002/jbm.a.30543.
7
Microstructure and Mechanical Properties of Galvanized-45 Steel/AZ91D Bimetallic Material by Liquid-Solid Compound Casting.液固复合铸造镀锌-45钢/AZ91D双金属材料的微观结构与力学性能
Materials (Basel). 2019 May 21;12(10):1651. doi: 10.3390/ma12101651.
8
Effect of zirconium-oxide ceramic surface treatments on the bond strength to adhesive resin.氧化锆陶瓷表面处理对与粘结树脂粘结强度的影响。
J Prosthet Dent. 2006 Jun;95(6):430-6. doi: 10.1016/j.prosdent.2006.03.016.
9
Development of analytical procedures for the determination of hexavalent chromium in corrosion prevention coatings used in the automotive industry.用于汽车工业的防腐涂层中六价铬的分析方法的开发。
Anal Bioanal Chem. 2008 May;391(2):587-97. doi: 10.1007/s00216-008-2051-7. Epub 2008 Apr 12.
10
A Two-Year Evaluation of Corrosion-Induced Damage to Hot Galvanized Reinforcing Steel B500SP in Chloride Contaminated Concrete.对氯化物污染混凝土中热镀锌钢筋B500SP腐蚀损伤的两年评估
Materials (Basel). 2020 Jul 25;13(15):3315. doi: 10.3390/ma13153315.

引用本文的文献

1
Research on Preventing High-Density Materials from Settling in Liquid Resin.防止高密度材料在液态树脂中沉降的研究
Materials (Basel). 2025 Jul 24;18(15):3469. doi: 10.3390/ma18153469.
2
Contributions to a More Realistic Characterization of Corrosion Processes on Cut Edges of Coated Metals Using Scanning Microelectrochemical Techniques, Illustrated by the Case of ZnAlMg-Galvanized Steel with Different Coating Densities.使用扫描微电化学技术对涂层金属切割边缘腐蚀过程进行更真实表征的贡献，以不同涂层密度的ZnAlMg镀锌钢为例说明
Materials (Basel). 2024 Apr 5;17(7):1679. doi: 10.3390/ma17071679.

本文引用的文献

1
Mechanical Characterization of Core-Shell Rubber/Epoxy Polymers for Automotive Structural Adhesives as a Function of Operating Temperature.用于汽车结构胶粘剂的核壳橡胶/环氧树脂聚合物随工作温度变化的力学特性
Polymers (Basel). 2021 Feb 27;13(5):734. doi: 10.3390/polym13050734.
2
Understanding the Toughening Mechanism of Silane Coupling Agents in the Interfacial Bonding in Steel Fiber-Reinforced Cementitious Composites.理解硅烷偶联剂在钢纤维增强水泥基复合材料界面粘结中的增韧机理。
ACS Appl Mater Interfaces. 2020 Sep 30;12(39):44163-44171. doi: 10.1021/acsami.0c12477. Epub 2020 Sep 22.
3
Silane adhesion mechanism in dental applications and surface treatments: A review.
硅烷在牙科应用和表面处理中的黏附机制：综述。
Dent Mater. 2018 Jan;34(1):13-28. doi: 10.1016/j.dental.2017.09.002. Epub 2017 Sep 29.
4
Dental applications for silane coupling agents.硅烷偶联剂的牙科应用。
J Oral Sci. 2016;58(2):151-5. doi: 10.2334/josnusd.16-0035.