Xuan Lixin, Wang Zhiqiang, Yang Xuan, Wu Xiao, Yang Junjiao, Zheng Shijun
AVIC Research Institute for Special Structures of Aeronautical Composite, Jinan 250023, China.
College of Chemistry, Beijing University of Chemical Technology, Beijing 100029, China.
Materials (Basel). 2025 Jul 24;18(15):3469. doi: 10.3390/ma18153469.
The applications of magnetic particles in anti-counterfeiting and anti-absorbing coatings and other functional materials are becoming increasingly widespread. However, due to their high density, the magnetic particles rapidly settle in organic resin media, significantly affecting the quality of the related products. Thereby, reducing the density of the particles is essential. To achieve this goal, high-density magnetic particles were coated onto the surface of hollow silica using anion-cation composite technology. Further, the silane coupling agent N-[3-(trimethoxysilyl)propyl]ethylenediamine was bonded to the surface of magnetic particles to form an amino-covered interfacial layer with a pH value of 9.28, while acrylic acid was polymerized and coated onto the surface of hollow silica to form a carboxyl-covered interfacial layer with a pH value of 4.65. Subsequently, the two materials were compounded to obtain a low-density composite magnetic material. The morphologies and structural compositions of the magnetic composite materials were studied by FTIR, SEM, SEM-EDS, XRD, and other methods. The packing densities of the magnetic composite materials were compared using the particle packing method, thereby solving the problem of magnetic particles settling in the resin solution.
磁性粒子在防伪、吸波涂层及其他功能材料中的应用越来越广泛。然而,由于其密度较高,磁性粒子在有机树脂介质中会迅速沉降,显著影响相关产品的质量。因此,降低粒子密度至关重要。为实现这一目标,采用阴阳离子复合技术将高密度磁性粒子包覆于中空二氧化硅表面。此外,将硅烷偶联剂N-[3-(三甲氧基硅基)丙基]乙二胺键合到磁性粒子表面,形成pH值为9.28的氨基包覆界面层,同时将丙烯酸聚合并包覆于中空二氧化硅表面,形成pH值为4.65的羧基包覆界面层。随后,将这两种材料复合,得到低密度复合磁性材料。通过傅里叶变换红外光谱(FTIR)、扫描电子显微镜(SEM)、扫描电子显微镜-能谱仪(SEM-EDS)、X射线衍射(XRD)等方法研究了磁性复合材料的形貌和结构组成。采用颗粒填充法比较了磁性复合材料的堆积密度,从而解决了磁性粒子在树脂溶液中沉降的问题。