Wang Yu, Chen Zhenbin, Awad Omar I, Qin Wanjian, Sultan Umair
School of Mechanics and Electronics Engineering, Hainan University, Haikou 570228, P. R. China.
National Engineering Research Center for Small and Special Precision Motors, Guiyang 550081, P. R. China.
ACS Omega. 2023 Sep 12;8(38):34959-34971. doi: 10.1021/acsomega.3c04416. eCollection 2023 Sep 26.
Water emulsified heavy fuel oil (HFO) has been a promising alternative fuel for reducing oil consumption and preventing environmental pollution. However, the intrinsic challenges such as fuel formula, emulsion stability, and preparation process normally limit its further applications in energy-saving and emission reduction applications. In this study, the glucose obtained from biomass was added to a dispersed-phase aqueous solution of water emulsified HFO to prepare a novel alternative emulsified fuel. First, based on the preliminary experimental design, the effects of glucose and surfactant on the stability of the HFO emulsion were systematically evaluated through the appearance of emulsion separation, droplet size distribution, and rheological characteristics. It indicated that the surfactant ratio, hydrophilic-lipophilic balance value, solution ratio, and glucose/water ratio had significant impacts on emulsion stability. Subsequently, the optimum range of influencing factors of emulsion stability was determined by a single factor experiment and determined by the response surface methodology based on the Box-Behnken design; the optimal values of the above factors were 2.439 v/v%, 5.807, 26.462 v/v%, and 35.729%, respectively. Under these conditions, an optimal glucose solution emulsified HFO with a uniform brown color and long-term stability was obtained, making the unseparated emulsion ratio reach 98% (lasting for 7 days at 85 °C). Meanwhile, it emerged that the influence of multifactor on emulsion stability was not a simple linear correlation, and there were significant interactions between the solution ratio and the surfactant ratio, as well as between the glucose/water ratio and the surfactant ratio.
水乳化重质燃料油(HFO)一直是一种很有前景的替代燃料,可用于减少油耗和防止环境污染。然而,诸如燃料配方、乳液稳定性和制备工艺等内在挑战通常限制了其在节能减排应用中的进一步应用。在本研究中,将从生物质中获得的葡萄糖添加到水乳化HFO的分散相水溶液中,以制备一种新型替代乳化燃料。首先,基于初步实验设计,通过乳液分离现象、液滴尺寸分布和流变特性,系统评估了葡萄糖和表面活性剂对HFO乳液稳定性的影响。结果表明,表面活性剂比例、亲水亲油平衡值、溶液比例和葡萄糖/水比例对乳液稳定性有显著影响。随后,通过单因素实验确定了乳液稳定性影响因素的最佳范围,并基于Box-Behnken设计通过响应面法确定;上述因素的最佳值分别为2.439 v/v%、5.807、26.462 v/v%和35.729%。在此条件下,获得了一种颜色均匀呈棕色且具有长期稳定性的最佳葡萄糖溶液乳化HFO,使未分离乳液比例达到98%(在85°C下持续7天)。同时发现,多因素对乳液稳定性的影响不是简单的线性关系,溶液比例与表面活性剂比例之间以及葡萄糖/水比例与表面活性剂比例之间存在显著的相互作用。