Graw Nico, Ruth Paul Niklas, Ernemann Tobias, Herbst-Irmer Regine, Stalke Dietmar
Institut für Anorganische Chemie, Georg-August-Universität Göttingen, Tammannstraße 4, Göttingen, Lower Saxony 37077, Germany.
J Appl Crystallogr. 2023 Sep 5;56(Pt 5):1315-1321. doi: 10.1107/S1600576723007203. eCollection 2023 Oct 1.
The MetalJet X-ray source provides indium α radiation with a wavelength even shorter than Ag radiation. This paper reports on problematic spectral impurities and presents possible countermeasures so that collection of data with excellent quality up to a high resolution is possible. It is demonstrated that these data can be used in the refinement of a multipole model, the results of which are used for a topological analysis to assess the bonding situation in a sulfur ylide compound.
MetalJet X射线源可提供波长甚至比银辐射更短的铟α辐射。本文报道了有问题的光谱杂质,并提出了可能的应对措施,以便能够高质量地收集高达高分辨率的数据。结果表明,这些数据可用于多极模型的精修,其结果用于拓扑分析以评估硫叶立德化合物中的键合情况。