Yang Shujiao, Han Jinxiu, Zhang Wei
Key Laboratory of Applied Surface and Colloid Chemistry, Ministry of Education, School of Chemistry and Chemical Engineering Shaanxi Normal University, Xi'an, 710119, P. R. China.
Chemistry. 2023 Dec 11;29(69):e202302770. doi: 10.1002/chem.202302770. Epub 2023 Oct 24.
Proton-coupled electron transfer (PCET) plays a crucial role in a diverse array of natural and artificial energy conversion processes. Herein, we will introduce the fundamentals of electrochemical PCET with a focus on its role in water splitting. Besides, perspectives of future development of PCET are presented with regard to the investigation of reaction mechanisms and the design of advanced electrocatalysts.
质子耦合电子转移（PCET）在各种各样的自然和人工能量转换过程中起着至关重要的作用。在此，我们将介绍电化学PCET的基本原理，重点关注其在水分解中的作用。此外，还从反应机理研究和先进电催化剂设计方面阐述了PCET未来发展的前景。
