Díaz-Perete Daniel, Hermoso-Orzáez Manuel Jesús, Terrados-Cepeda Julio, Silva-Romano Pedro, Martin-Doñate Cristina
Department of Graphic Engineering, Design and Projects, University of Jaén, 23071, Jaén, Spain.
VALORIZA - Research Center for Endogenous Resource Valorization, Polytechnic Institute of Portalegre, Portugal IP Portalegre - Polytechnic Institute of Portalegre, Portalegre, Portugal.
Heliyon. 2023 Sep 15;9(9):e20194. doi: 10.1016/j.heliyon.2023.e20194. eCollection 2023 Sep.
The global production of polymer materials has exploded in the last few decades. Their mechanical properties, erosion and corrosion resistance, good performance as insulation materials, and their ease and flexibility of manufacturing have made polymers one of the most widely used materials in the industry and in daily life. Several institutions and governments are beginning to raise serious environmental and ecological concerns with international impact soon, due to the increasing level of polymer production, which does not seem to be slowing down. It is necessary for the scientific community to make efforts in the development and evaluation of new methodologies to enable the inclusion of these types of materials in the circular economy of various production sectors. This is important in order to reduce the ecological impact caused by the current global production level of polymers. One of the most used methods for the recovery of polymeric materials is energy valorization through thermochemical processes. An example of this is thermal gasification using fuels composed of biomass and a mixture of polymeric waste from electrical and electronic equipment (WEEE). Through this thermochemical process, high-energy value synthesis gas, with a high concentration of hydrogen, is obtained on one hand, while waste products in the form of chars, ashes and slag are generated on the other hand. This manuscript presents a detailed study methodology that begins with chemical analysis of the raw material and includes subsequent analysis of mechanical results for the revaluation of these residual inert by-products, using them as partial substitutes in cement clinker to produce building mortars. This described methodology influences directly in the LCC (Life Cycle Costing) of final designed products in plastic and extend material life cycle Plastic materials are here to stay, so the study and optimization of polymer waste recovery processes are vital in achieving the Sustainable Development Goals (SDGs) set by the European Union in terms of efficiency and sustainability. It is also the only possible way to create an environmentally sustainable future world for future generations. After applying the described methodology, the mechanical test results show that the modified mortars exhibit established behaviour during the hardening time and similar strength growth compared to commercial mortars. The maximum mechanical strengths achieved, including compressive and flexural strength, make modified mortars a viable choice for several applications in the civil engineering sector.
在过去几十年里,全球聚合物材料的产量呈爆炸式增长。它们的机械性能、抗侵蚀和抗腐蚀性能、作为绝缘材料的良好性能以及制造的简便性和灵活性,使聚合物成为工业和日常生活中使用最广泛的材料之一。由于聚合物产量不断增加且似乎没有放缓的迹象,一些机构和政府很快开始对具有国际影响的环境和生态问题表示严重关切。科学界有必要努力开发和评估新方法,以便将这类材料纳入各生产部门的循环经济中。这对于减少当前全球聚合物生产水平造成的生态影响至关重要。回收聚合物材料最常用的方法之一是通过热化学过程进行能源增值。其中一个例子是使用由生物质和电子电气设备中的聚合物废料混合物组成的燃料进行热气化。通过这种热化学过程,一方面可获得具有高氢浓度的高能量值合成气,另一方面会产生炭、灰和炉渣形式的废料。本手稿介绍了一种详细的研究方法,该方法从原材料的化学分析开始,随后对这些残余惰性副产品进行机械性能结果分析,以便重新评估它们,并将其用作水泥熟料的部分替代品来生产建筑砂浆。所描述的这种方法直接影响最终设计塑料制品的生命周期成本(LCC),并延长材料的生命周期。塑料材料将继续存在,因此研究和优化聚合物废料回收过程对于实现欧盟设定的可持续发展目标(SDGs)在效率和可持续性方面至关重要。这也是为子孙后代创造一个环境可持续的未来世界的唯一可行途径。应用所描述的方法后,机械测试结果表明,与商业砂浆相比,改性砂浆在硬化过程中表现出既定的性能,强度增长相似。所达到的最大机械强度,包括抗压强度和抗弯强度,使改性砂浆成为土木工程领域多种应用的可行选择。