Angew Chem Int Ed Engl. 2023 Dec 11;62(50):e202309585. doi: 10.1002/anie.202309585. Epub 2023 Oct 13.
This invited Team Profile was created by the teams of Dana D. Medina, LMU Munich, Germany; Laura M. Salonen, CINBIO, University of Vigo, Spain ; Tim Kowalczyk, Western Washington University, Bellingham, USA; João Rocha, CICECO, University of Aveiro, Portugal; and Akshay Rao, University of Cambridge, UK. They recently published an article on a three-component synthesis strategy for the formation of covalent organic frameworks (COFs) containing extended fused aromatics, which enables the synthesis of the building blocks and COF on a similar time scale. The methodology was also successfully applied to produce highly crystalline, preferentially oriented thin films with nanostructured surfaces on various substrates. "Building Blocks and COFs Formed in Concert-Three-Component Synthesis of Pyrene-Fused Azaacene Covalent Organic Framework in the Bulk and as Films", L. Frey, O. Oliveira, A. Sharma, R. Guntermann, S. P. S Fernandes, K. M. Cid-Seara, H. Abbay, H. Thornes, J. Rocha, M. Döblinger, T. Kowalczyk, A. Rao, L. M. Salonen, D. D. Medina, Angew. Chem. Int. Ed. 2023, 62, e202302872.
这篇特邀团队简介由德国慕尼黑路德维希-马克西米利安大学的达纳·D·梅迪纳团队、西班牙维戈大学CINBIO的劳拉·M·萨洛宁团队、美国贝灵汉西华盛顿大学的蒂姆·科瓦尔奇克、葡萄牙阿威罗大学CICECO的若昂·罗查以及英国剑桥大学的阿克沙伊·拉奥共同撰写。他们最近发表了一篇关于形成含有扩展稠合芳烃的共价有机框架（COF）的三组分合成策略的文章，该策略能够在相似的时间尺度上合成构建块和COF。该方法还成功应用于在各种基底上制备具有纳米结构表面的高度结晶、择优取向的薄膜。《协同形成的构建块和COF—— bulk相中芘稠合氮杂并苯共价有机框架及薄膜的三组分合成》，L. 弗雷、O. 奥利维拉、A. 沙尔马、R. 贡特曼、S. P. S. 费尔南德斯、K. M. 西德-西拉、H. 阿贝、H. 索恩斯、J. 罗查、M. 德布林格、T. 科瓦尔奇克、A. 拉奥、L. M. 萨洛宁、D. D. 梅迪纳，《德国应用化学》，2023年，第62卷，e202302872。
