Exploring Hydrochars from Lignocellulosic Wastes as Secondary Carbon Fuels for Sustainable Steel Production.

This study investigates the suitability of different lignocellulosic sources, namely eucalyptus, apple bagasse, and out-of-use wood, for injection into blast furnaces (BFs). While wastes possess carbon potential, their high moisture renders them unsuitable for direct energy utilization. Additionally, the P and K impurities, particularly in apple bagasse, can pose operational and product quality challenges in BF. Thus, different thermochemical processes were performed to convert raw biomass into a more suitable carbon fuel. Low-temperature carbonization was selected for eucalyptus, yielding a biochar with properties closer to the low-rank coal. Hydrothermal carbonization was chosen for apple bagasse and out-of-use wood, resulting in hydrochars with enhanced fuel characteristics and fewer adverse inorganic species but still limiting the amount in binary PCI blends. Thermogravimetry evaluated the cause-effect relationships between coal and coal- and bio-based chars during co-pyrolysis, co-combustion and CO-gasification. No synergistic effects for char formation were observed, while biochars benefited ignition and reactivity during combustion at the programmed temperature. From heat-flow data in combustion, the high calorific values of the chars were well predicted. The CO-gasification profiles of in situ chars revealed that lignin-rich hydrochars exhibited higher reactivity and conversion than those with a higher carbohydrate content, making them more suitable for gasification applications.