Catalytic Gasification of Petroleum Coke with Different Ratios of KCO and Evolution of the Residual Coke Structure.

The catalytic gasification of petroleum coke with different ratios of KCO was investigated by a thermogravimetric analyzer (TGA) using the non-isothermal method. The initial, peak, and final gasification temperatures of the petroleum coke decreased greatly as the amount of KCO increased, and the catalytic reaction became saturated at a concentration of K higher than 5 mmol/g; with the further increase in catalyst; the gasification rate varied slightly, but no inhibition effect was observed. The vaporization of the catalyst was confirmed during the gasification at high temperatures. The structural evolution of the residual coke with different carbon conversions was examined by X-ray diffraction (XRD), Raman spectroscopy, and N adsorption analyses during gasification with and without the catalyst. The results showed that the carbon crystallite structure of the residual coke varied in the presence of the catalyst. As the carbon conversion increased, the structure of the residual coke without the catalyst became more ordered, and the number of aromatic rings decreased, while the graphitization degree of the residual coke in the presence of the catalyst decreased. Meanwhile, the surface area and pore volume of petroleum coke increased in the gasification process of the residual coke, irrespective of the presence of the catalyst. However, the reactivity of the residual coke did not change much with the variation in the carbon and pore structure during the reaction.