• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利：CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法，用中文像聊天一样搜索，搜遍4000万医学文献。AI智能推荐，让科研检索更轻松。

立即免费搜索

文件翻译

保留排版，准确专业，支持PDF/Word/PPT等文件格式，支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述，25分钟生成高质量综述，智能提取关键信息，辅助科研写作。

立即免费体验

深入了解Pt与MnO在CO氧化中的金属-载体相互作用。

Insight into the Metal-Support Interaction of Pt and -MnO in CO Oxidation.

作者信息

Zhang Tiantian, Xu Jiacheng, Sun Yan, Fang Shiyu, Wu Zuliang, Gao Erhao, Zhu Jiali, Wang Wei, Yao Shuiliang, Li Jing

机构信息

School of Environmental Science and Engineering, Changzhou University, Changzhou 213164, China.

School of Material Science and Engineering, Changzhou University, Changzhou 213164, China.

出版信息

Molecules. 2023 Sep 29;28(19):6879. doi: 10.3390/molecules28196879.

DOI:10.3390/molecules28196879
PMID:37836722
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC10574042/
Abstract

Pt-based catalysts exhibit unique catalytic properties in many chemical reactions. In particular, metal-support interactions (MSI) greatly improve catalytic activity. However, the current MSI mechanism between platinum (Pt) and the support is not clear enough. In this paper, the interaction of 1 wt% Pt nanoparticles (NPs) on -MnO in carbon monoxide (CO) oxidation was studied. The Pt on -MnO inhibited CO oxidation below 210 °C but promoted it above 210 °C. A Pt/-MnO catalyst contains more Pt and less Pt. The results of operando DRIFTS-MS show that surface-terminal-type oxygen (M=O) plays an important role in CO oxidation. When the temperature was below 210 °C, Mn=O consumption on Pt/-MnO was less than -MnO due to Pt inhibition on CO oxidation. When the temperature was above 210 °C, Pt was reduced to Pt, and Mn=O consumption due to CO oxidation was greater than -MnO. The interaction of Pt and -MnO is proposed.

摘要

基于铂的催化剂在许多化学反应中表现出独特的催化性能。特别是，金属-载体相互作用（MSI）极大地提高了催化活性。然而，目前铂（Pt）与载体之间的MSI机制尚不够清晰。本文研究了1 wt%的铂纳米颗粒（NPs）负载在MnO上在一氧化碳（CO）氧化反应中的相互作用。负载在MnO上的Pt在210℃以下抑制CO氧化，但在210℃以上促进CO氧化。Pt/MnO催化剂含有较多的Pt和较少的Pt。原位漫反射红外傅里叶变换光谱-质谱（operando DRIFTS-MS）结果表明，表面端基型氧（M=O）在CO氧化中起重要作用。当温度低于210℃时，由于Pt对CO氧化的抑制作用，Pt/MnO上的Mn=O消耗比MnO少。当温度高于210℃时，Pt被还原为Pt，并且由于CO氧化导致的Mn=O消耗大于MnO。本文提出了Pt与MnO的相互作用。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/703f/10574042/3cffce79d0a9/molecules-28-06879-g013.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/703f/10574042/f262c99c1e8e/molecules-28-06879-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/703f/10574042/883dd92b7639/molecules-28-06879-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/703f/10574042/a9bde0f2d1aa/molecules-28-06879-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/703f/10574042/966a5dcfad7d/molecules-28-06879-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/703f/10574042/0d81f0b449ca/molecules-28-06879-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/703f/10574042/725227494372/molecules-28-06879-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/703f/10574042/6a03a32888f1/molecules-28-06879-g007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/703f/10574042/581f8ea2c21d/molecules-28-06879-g008.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/703f/10574042/4049d2caed9f/molecules-28-06879-g009.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/703f/10574042/2d0437a837ef/molecules-28-06879-g010.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/703f/10574042/b6f4714ef698/molecules-28-06879-g011.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/703f/10574042/0403ffb84030/molecules-28-06879-g012.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/703f/10574042/3cffce79d0a9/molecules-28-06879-g013.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/703f/10574042/f262c99c1e8e/molecules-28-06879-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/703f/10574042/883dd92b7639/molecules-28-06879-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/703f/10574042/a9bde0f2d1aa/molecules-28-06879-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/703f/10574042/966a5dcfad7d/molecules-28-06879-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/703f/10574042/0d81f0b449ca/molecules-28-06879-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/703f/10574042/725227494372/molecules-28-06879-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/703f/10574042/6a03a32888f1/molecules-28-06879-g007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/703f/10574042/581f8ea2c21d/molecules-28-06879-g008.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/703f/10574042/4049d2caed9f/molecules-28-06879-g009.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/703f/10574042/2d0437a837ef/molecules-28-06879-g010.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/703f/10574042/b6f4714ef698/molecules-28-06879-g011.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/703f/10574042/0403ffb84030/molecules-28-06879-g012.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/703f/10574042/3cffce79d0a9/molecules-28-06879-g013.jpg

相似文献

1
Insight into the Metal-Support Interaction of Pt and -MnO in CO Oxidation.深入了解Pt与MnO在CO氧化中的金属-载体相互作用。
Molecules. 2023 Sep 29;28(19):6879. doi: 10.3390/molecules28196879.
2
Regulating the Pt-MnO Interaction and Interface for Room Temperature Formaldehyde Oxidation.调控 Pt-MnO 相互作用和界面实现室温甲醛氧化。
Inorg Chem. 2023 Jan 16;62(2):904-915. doi: 10.1021/acs.inorgchem.2c03731. Epub 2023 Jan 4.
3
Enhancing oxidation reaction over Pt-MnO catalyst by activation of surface oxygen.通过激活表面氧来增强 Pt-MnO 催化剂的氧化反应。
J Environ Sci (China). 2023 Dec;134:117-125. doi: 10.1016/j.jes.2023.01.011. Epub 2023 Jan 17.
4
Tunable metal-support interaction of Pt/CeO catalyst via surfactant-assisted strategy: Insight into the total oxidation of CO and toluene.通过表面活性剂辅助策略实现Pt/CeO催化剂的可调金属-载体相互作用：对CO和甲苯完全氧化的见解
J Hazard Mater. 2022 Feb 15;424(Pt C):127601. doi: 10.1016/j.jhazmat.2021.127601. Epub 2021 Oct 28.
5
Exploring the roles of oxygen species in H oxidation at β-MnO surfaces using operando DRIFTS-MS.使用原位漫反射红外傅里叶变换光谱-质谱联用技术探究氧物种在β-二氧化锰表面氢氧化反应中的作用。
Commun Chem. 2022 Aug 20;5(1):97. doi: 10.1038/s42004-022-00717-0.
6
Reduced graphene oxide as an effective promoter to the layered manganese oxide-supported Ag catalysts for the oxidation of ethyl acetate and carbon monoxide.还原氧化石墨烯作为层状氧化锰负载银催化剂用于乙酸乙酯和一氧化碳氧化的有效促进剂。
J Hazard Mater. 2022 Jun 5;431:128518. doi: 10.1016/j.jhazmat.2022.128518. Epub 2022 Feb 19.
7
Fabrication of Highly Dispersed Co-Fe-Doped-δ-MnO Catalyst by a Facile Redox-Driving MOFs-Derived Method for Low-Temperature Oxidation of Toluene.通过简便的氧化还原驱动 MOFs 衍生法制备高度分散的 Co-Fe 掺杂 δ-MnO 催化剂，用于甲苯的低温氧化。
ACS Appl Mater Interfaces. 2022 Dec 7;14(48):53872-53883. doi: 10.1021/acsami.2c16620. Epub 2022 Nov 25.
8
Insight into the Crystal Structures and Surface Property of Manganese Oxide on CO Catalytic Oxidation Performance.锰氧化物的晶体结构和表面性质对CO催化氧化性能的影响
Inorg Chem. 2021 Apr 19;60(8):5812-5820. doi: 10.1021/acs.inorgchem.1c00144. Epub 2021 Mar 30.
9
Pt and Mo Co-Decorated MnO Nanorods with Superior Resistance to HO, Sintering, and HCl for Catalytic Oxidation of Chlorobenzene.铂和钼共修饰的MnO纳米棒对羟基自由基、烧结和HCl具有优异抗性用于氯苯的催化氧化
Environ Sci Technol. 2021 Oct 19;55(20):14204-14214. doi: 10.1021/acs.est.1c05086. Epub 2021 Oct 8.
10
Enhancement of catalytic toluene combustion over Pt-CoO catalyst through in-situ metal-organic template conversion.通过原位金属有机模板转化增强 Pt-CoO 催化剂对甲苯的催化燃烧。
Chemosphere. 2021 Jan;262:127738. doi: 10.1016/j.chemosphere.2020.127738. Epub 2020 Jul 21.

引用本文的文献

1
Pt Nanoparticles on Multi-Walled Carbon Nanotubes with High CO Tolerance for Methanol Electrooxidation.具有高抗一氧化碳性能的多壁碳纳米管负载铂纳米颗粒用于甲醇电氧化
Molecules. 2024 Oct 23;29(21):5015. doi: 10.3390/molecules29215015.

本文引用的文献

1
Exploring the roles of oxygen species in H oxidation at β-MnO surfaces using operando DRIFTS-MS.使用原位漫反射红外傅里叶变换光谱-质谱联用技术探究氧物种在β-二氧化锰表面氢氧化反应中的作用。
Commun Chem. 2022 Aug 20;5(1):97. doi: 10.1038/s42004-022-00717-0.
2
Regulating the Pt-MnO Interaction and Interface for Room Temperature Formaldehyde Oxidation.调控 Pt-MnO 相互作用和界面实现室温甲醛氧化。
Inorg Chem. 2023 Jan 16;62(2):904-915. doi: 10.1021/acs.inorgchem.2c03731. Epub 2023 Jan 4.
3
Thermal-Driven Optimization of the Strong Metal-Support Interaction of a Platinum-Manganese Oxide Octahedral Molecular Sieve to Promote Toluene Oxidation: Effect of the Interface Pt-O-Mn.
热驱动优化铂-锰氧化物八面体分子筛的强金属-载体相互作用以促进甲苯氧化：界面Pt-O-Mn的作用
ACS Appl Mater Interfaces. 2022 Dec 28;14(51):56790-56800. doi: 10.1021/acsami.2c16923. Epub 2022 Dec 16.
4
The preparation of ultrastable Al doped CeO supported Au catalysts: Strong metal-support interaction for superior catalytic activity towards CO oxidation.超稳定铝掺杂氧化铈负载金催化剂的制备：强金属-载体相互作用对一氧化碳氧化具有优异的催化活性
J Colloid Interface Sci. 2022 Dec;627:53-63. doi: 10.1016/j.jcis.2022.07.007. Epub 2022 Jul 8.
5
Modulate the metal support interactions to optimize the surface-interface features of Pt/CeO catalysts for enhancing the toluene oxidation.调节金属载体相互作用以优化Pt/CeO催化剂的表面-界面特性，从而增强甲苯氧化性能。
J Hazard Mater. 2022 Feb 15;424(Pt C):127505. doi: 10.1016/j.jhazmat.2021.127505. Epub 2021 Oct 15.
6
Pt/MnO for toluene mineralization via ozonation catalysis at low temperature: SMSI optimization of surface oxygen species.通过低温臭氧催化氧化作用实现甲苯矿化：表面氧物种的强金属-载体相互作用优化。
Chemosphere. 2022 Jan;286(Pt 3):131754. doi: 10.1016/j.chemosphere.2021.131754. Epub 2021 Aug 2.
7
Simple strategy for the construction of oxygen vacancies on α-MnO catalyst to improve toluene catalytic oxidation.在α-MnO催化剂上构建氧空位以改善甲苯催化氧化的简单策略。
J Hazard Mater. 2021 May 5;409:125020. doi: 10.1016/j.jhazmat.2020.125020. Epub 2020 Dec 31.
8
Facile fabrication of flower-like MnO hollow microspheres as high-performance catalysts for toluene oxidation.简便制备花状MnO空心微球作为甲苯氧化的高性能催化剂。
J Hazard Mater. 2021 Apr 15;408:124458. doi: 10.1016/j.jhazmat.2020.124458. Epub 2020 Nov 4.
9
Catalytic decomposition and mechanism of formaldehyde over Pt-AlO molecular sieves at room temperature.室温下Pt-AlO分子筛上甲醛的催化分解及机理
Phys Chem Chem Phys. 2017 Mar 8;19(10):6957-6963. doi: 10.1039/c6cp08223h.
10
Enhanced catalytic and supercapacitor activities of DNA encapsulated β-MnO₂ nanomaterials.DNA包裹的β-MnO₂纳米材料的增强催化和超级电容器活性
Phys Chem Chem Phys. 2014 Oct 21;16(39):21846-59. doi: 10.1039/c4cp02884h. Epub 2014 Sep 9.