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通过喷雾干燥实现多功能杂化材料设计:远不止于干燥

Multifunctional, Hybrid Materials Design via Spray-Drying: Much more than Just Drying.

作者信息

Wintzheimer Susanne, Luthardt Leoni, Cao Kiet Le Anh, Imaz Inhar, Maspoch Daniel, Ogi Takashi, Bück Andreas, Debecker Damien P, Faustini Marco, Mandel Karl

机构信息

Inorganic Chemistry, Department of Chemistry and Pharmacy, Friedrich-Alexander-Universität Erlangen-Nürnberg, Egerlandstraße 1, 91058, Erlangen, Germany.

Fraunhofer-Institute for Silicate Research ISC, Neunerplatz 2, 97082, Würzburg, Germany.

出版信息

Adv Mater. 2023 Nov;35(47):e2306648. doi: 10.1002/adma.202306648. Epub 2023 Oct 15.

DOI:10.1002/adma.202306648
PMID:37840431
Abstract

Spray-drying is a popular and well-known "drying tool" for engineers. This perspective highlights that, beyond this application, spray-drying is a very interesting and powerful tool for materials chemists to enable the design of multifunctional and hybrid materials. Upon spray-drying, the confined space of a liquid droplet is narrowed down, and its ingredients are forced together upon "falling dry." As  detailed in this article, this enables the following material formation strategies either individually or even in combination: nanoparticles and/or molecules can be assembled; precipitation reactions as well as chemical syntheses can be performed; and templated materials can be designed. Beyond this, fragile moieties can be processed, or "precursor materials" be prepared. Post-treatment of spray-dried objects eventually enables the next level in the design of complex materials. Using spray-drying to design (particulate) materials comes with many advantages-but also with many challenges-all of which are outlined here. It is believed that multifunctional, hybrid materials, made via spray-drying, enable very unique property combinations that are particularly highly promising in myriad applications-of which catalysis, diagnostics, purification, storage, and information are highlighted.

摘要

喷雾干燥是工程师们常用且熟知的“干燥工具”。本文观点强调,除了这一应用外,喷雾干燥对于材料化学家而言是一种非常有趣且强大的工具,可用于设计多功能和混合材料。在喷雾干燥过程中,液滴的受限空间会缩小,其成分在“变干”过程中被迫聚集在一起。如本文详细所述,这使得以下材料形成策略能够单独或甚至组合实现:纳米颗粒和/或分子可以组装;可以进行沉淀反应以及化学合成;可以设计模板材料。除此之外,还可以处理易碎部分或制备“前驱体材料”。对喷雾干燥产物进行后处理最终能够实现复杂材料设计的更高水平。利用喷雾干燥来设计(颗粒状)材料有诸多优点,但也面临许多挑战——本文将对所有这些进行概述。据信,通过喷雾干燥制成的多功能混合材料具有非常独特的性能组合,在众多应用中极具前景——本文重点介绍了催化、诊断、净化、存储和信息等应用。

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