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筛选用于黑土氮素保持的最佳改性生物炭。

Screening the optimal modified biochar for nitrogen retention in black soil.

作者信息

Wang Yifan, Li Dannan, Liu Hechun, Wu Di, Ai Yunhe, Li Jianen, Xu Liang, Liu Wei, Qu Jianhua, Tao Yue, Wang Jing, Wang Jianzhi, Zhang Ying

机构信息

School of Resources and Environment, Northeast Agricultural University, Harbin, 150030, People's Republic of China.

出版信息

Environ Sci Pollut Res Int. 2023 Nov;30(52):113088-113104. doi: 10.1007/s11356-023-30295-0. Epub 2023 Oct 17.

Abstract

Reducing the environmental problems caused by nitrogen loss and nitrogen pollution is of great significance. The addition of biochar to soil is a new method for increasing nitrogen interception due to the special structural and physicochemical properties of biochar. The optimal modified biochar was screened out after acid-base modification and batch adsorption test in this paper. And then the effects of different soil and biochar mixing methods on soil physicochemical properties and nitrogen adsorption and retention were explored through soil column leaching test. The results showed that the biochar with a pyrolysis temperature of 700 °C had the best adsorption effect on nitrogen after being modified by 0.1 mol/L HCI, and the adsorption capacity of nitrate nitrogen reached 121.46 mg/g. The adsorption process of ammonia nitrogen and nitrate nitrogen conformed to the Langmuir model and was mainly homogeneous monolayer. After mixing the selected modified biochar with black soil, the pH increased by 4.77%, the content of ammonia nitrogen increased by 4.89%, and the nitrate content increased by 16.62%. In this study, the adsorption effect of biochar on nitrogen in black soil was discussed, so as to explore the optimal use of biochar in soil, which provided some reference basis for the relevant research.

摘要

减少氮素流失和氮污染所造成的环境问题具有重要意义。由于生物炭特殊的结构和理化性质,向土壤中添加生物炭是一种增加氮素截留的新方法。本文通过酸碱改性和批次吸附试验筛选出了最优改性生物炭。然后通过土柱淋溶试验探究了不同土壤与生物炭混合方式对土壤理化性质及氮素吸附保留的影响。结果表明,700℃热解温度的生物炭经0.1mol/L HCI改性后对氮素的吸附效果最佳,对硝态氮的吸附量达121.46mg/g。氨氮和硝态氮的吸附过程符合Langmuir模型,主要为均匀单分子层吸附。将筛选出的改性生物炭与黑土混合后,pH升高了4.77%,氨氮含量增加了4.89%,硝态氮含量增加了16.62%。本研究探讨了生物炭对黑土中氮素的吸附效果,以探索生物炭在土壤中的最佳利用方式,为相关研究提供了一定的参考依据。

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