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将生物基物质转化为生物炭,以增强其对养分的吸附和保留能力。

Conversion of biobased substances into biochar to enhances nutrient adsorption and retention capacity.

机构信息

ICAR Research Complex for NEH Region, Sikkim Centre, Tadong, Gangtok, Sikkim, 737102, India.

出版信息

Environ Monit Assess. 2024 Jan 12;196(2):142. doi: 10.1007/s10661-024-12317-7.

Abstract

Reducing the environmental issues brought on by nutrients especially nitrogen pollution and loss is important. Owing to its unique composition and physico-chemical characteristics, biomass-derived biochar exhibits varying degrees of adsorption and interception for all types of soil nutrients. Thus, a novel way to improve nutrient absorption in the soil is to include biomass derived biochar into it. Various biomass-derived biochar from locally available biobased substances was synthesized through low-cost portable charring kiln. It has been quantified the influence of four biobased substances and three pyrolysis temperature on different morphomineralogical characteristics of biochar for utilizing as low-cost sorbent to manage nutrient adsorption and retention capacity. The morphomineralogical characteristics were principally manipulated by feedstocks rather than pyrolysis temperature. Higher porosity and surface area of biomass-derived biochar illustrated its soil structural modification and nutrient retention capacity along with their utilization for adsorbents. With increase in pyrolysis temperature, the adsorption capacity of biochar for NH-N and NO-N was gradually weakened and gradually enhanced respectively. The adsorption process of ammonia nitrogen and nitrate nitrogen conformed to the Langmuir model and the fitted KL value was less than 1 indicating that the adsorption process was uniform monolayer adsorption and the adsorption of biochar was favorable adsorption. With increase in biochar application rate the leaching of NO-N decreased having higher at 2.5 t ha application rate followed by 5 t ha and lower at 7.5 t ha. In packed soil column, the NH-N in leachate was maximum in T (18.6), followed by T (17.9), T (17.3) and minimum in T (17.2) at same application rate of manures and biochar. Finally, results also revealed that packed soil column performed better as compared with intact soil column to retain soil nutrient and hence, leaching potential of nutrient was less in packed column than intact soil column. In conclusion, biomass-derived biochar can enhance the amount of nutrient that is absorbed into the soil while decreasing the loss of nutrient from the soil in the form of ammonia and nitrate. To sum up, biomass-derived biochar can increase the adsorption amount of the nitrogen and reduce the loss of ammonia nitrogen and nitrate nitrogen in the soil, thus retaining the nitrogen.

摘要

减少营养物质(特别是氮污染和流失)带来的环境问题非常重要。由于生物质衍生生物炭独特的组成和物理化学特性,它对各种类型的土壤养分表现出不同程度的吸附和截留。因此,一种提高土壤养分吸收的新方法是将生物质衍生生物炭纳入其中。通过低成本便携式炭化窑合成了各种来自本地生物基物质的生物质衍生生物炭。定量研究了四种生物基物质和三种热解温度对生物炭不同形态矿物学特征的影响,以利用低成本吸附剂来管理养分的吸附和保持能力。形态矿物学特征主要受原料控制,而不受热解温度影响。生物质衍生生物炭具有更高的孔隙率和比表面积,说明其具有土壤结构改良和养分保持能力,可用作吸附剂。随着热解温度的升高,生物炭对 NH-N 和 NO-N 的吸附能力逐渐减弱,分别逐渐增强。氨氮和硝酸盐氮的吸附过程符合朗缪尔模型,拟合的 KL 值均小于 1,表明吸附过程为均匀的单层吸附,生物炭的吸附为有利吸附。随着生物炭施用量的增加,NO-N 的淋失量逐渐减少,在 2.5 t ha 的施用量下最高,其次是 5 t ha,在 7.5 t ha 的施用量下最低。在填充土壤柱中,在相同的肥料和生物炭施用量下,浸出液中 NH-N 在 T(18.6)中最高,其次是 T(17.9)、T(17.3),T(17.2)中最低。最后,结果还表明,与完整土壤柱相比,填充土壤柱更能保留土壤养分,因此,填充柱中养分的淋失潜力小于完整土壤柱。总之,生物质衍生生物炭可以增加土壤中吸收的养分数量,同时减少以氨和硝酸盐形式从土壤中流失的养分。综上所述,生物质衍生生物炭可以增加氮的吸附量,减少土壤中氨氮和硝酸盐氮的损失,从而保留氮。

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