Electrochemical C(sp)-H/N-H "formal" cross-dehydrogenative coupling of olefins with benzotriazoles for synthesis of -vinyl benzotriazoles.
作者信息
Lv Jin-Feng, Tan Yu-Fang, Zhao Ya-Nan, Yang Dan, He Yan-Hong, Guan Zhi
机构信息
Key Laboratory of Applied Chemistry of Chongqing Municipality, School of Chemistry and Chemical Engineering, Southwest University, Chongqing 400715, China.
Analytical and Testing Center, Southwest University, Chongqing, 400715, China.
出版信息
Org Biomol Chem. 2023 Nov 1;21(42):8488-8493. doi: 10.1039/d3ob01300f.
The paper details an electrochemical method that couples olefins with benzotriazoles to form C(sp)-N bonds, enabling the synthesis of -vinyl benzotriazoles in moderate to good yields. BuNI functions as both an electrolyte and an iodine mediator, and the method does not require oxidants or metals. It is a highly atom-economical and clean reaction, with hydrogen as the sole byproduct.
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