Department of Physics, Texas Southern University, Houston, TX 77004.
Department of Mathematical Sciences, Texas Southern University, Houston, TX 77004.
Health Phys. 2024 Jan 1;126(1):25-36. doi: 10.1097/HP.0000000000001765. Epub 2023 Oct 20.
The former Panna Maria mill was a uranium recovery facility that operated from 1979 to December 1992. Sulfuric acid leach was used to process several tons of ore daily. Therefore, the groundwater was sampled at the site to monitor the concentration of background chemical pollutants. The purpose of this study was to perform exploratory data analysis to evaluate whether the arsenic, nickel, selenium, sulfate, and uranium concentrations were in accord with state-regulated groundwater drinking standards at the site. To accomplish this, a substitution method was used to replace concentration values that were below measurable ranges of well monitoring units. Additionally, random forest regression was employed to account for missing not-at-random values in the dataset. Groundwater samples collected in wells before the facility began operations were used to determine an upper bound on background pollutants consistent with US Environmental Protection Agency Standards. The upper tolerance limit comprising 90% of the groundwater sample at a confidence coefficient of 95% was used to establish alternate concentration limits for each chemical based on well data from the National Uranium Resource Hydrogeochemical and Stream Sediment Reconnaissance program. Results obtained in this analysis establish a baseline on the chemical concentrations in the background groundwater at the former Panna Maria mill.
前帕纳玛利亚工厂是一个铀回收设施,从 1979 年运营到 1992 年 12 月。采用硫酸浸出法每天处理数吨矿石。因此,在现场抽取地下水样以监测背景化学污染物的浓度。本研究的目的是进行探索性数据分析,以评估砷、镍、硒、硫酸盐和铀的浓度是否符合该地点的国家监管地下水饮用水标准。为此,采用替代方法来替代低于井监测单元可测量范围的浓度值。此外,还采用随机森林回归来解释数据集中缺失的非随机值。在设施开始运营之前从井中采集的地下水样本用于确定与美国环境保护署标准一致的背景污染物的上限。置信系数为 95%时,包含 90%地下水样本的上限容忍度用于根据国家铀资源水文地球化学和河流沉积物勘查计划的井数据为每种化学物质建立替代浓度限值。本分析得出的结果确定了前帕纳玛利亚工厂背景地下水中化学物质浓度的基线。