Molecularly modulating solvation structure and electrode interface enables dendrite-free zinc-ion batteries.

The performance of aqueous Zn ion batteries (AZIBs) is hindered by the uncontrollable growth of Zn dendrites and side reactions at the Zn anode/electrolyte interface. Here, we introduce low-cost glucosamine hydrochloride (GLA) into the ZnSO electrolyte system to modulate the Zn anode/electrolyte interface and the solvation structure of Zn, which leads to improved reversibility of Zn plating/striping. Through experimental and theoretical analyses, we demonstrate that GLA molecules could adsorp on the Zn metal surface to form a new interface with reduced active water, effectively suppressing water-induced side reactions. Moreover, after adding GLA, the flux of Zn ions is regulated, the desolvation of the primary [Zn(HO)] ions is promoted, and the Zn dendrite growth is significantly inhibited. Consequently, superior cyclic stability with a lower voltage hysteresis is simultaneously achieved in a Zn//Zn symmetric cell. When coupled with the MnO cathode, the fabricated Zn-Mn batteries with the modified ZnSO + GLA electrolyte system deliver boosted capacity, improved long-term cycling stability, and better self-discharge performance. This work provides insight into the development of high-efficient and low-cost electrolytes for high-performance Zn-based energy storage devices.