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具有卓越水下性能的耐用型水凝胶基润滑复合涂层。

Durable hydrogel-based lubricated composite coating with remarkable underwater performances.

作者信息

Zhang Jiawei, Guan Yingxin, Zhang Qin, Wang Tianyu, Wang Ming, Zhang Zhixin, Gao Yang, Gao Guanghui

机构信息

Polymeric and Soft Materials Laboratory, School of Chemical Engineering and Advanced Institute of Materials Science, Changchun University of Technology, Changchun 130012, China.

Polymeric and Soft Materials Laboratory, School of Chemistry and Life Science and Advanced Institute of Materials Science, Changchun University of Technology, Changchun 130012, China.

出版信息

J Colloid Interface Sci. 2024 Jan 15;654(Pt A):568-580. doi: 10.1016/j.jcis.2023.09.193. Epub 2023 Oct 6.

Abstract

HYPOTHESIS

Hydrogel coatings have received great attention in the field of such as medical devices, water treatment membranes, flexible electronics, and marine antifouling. However, when it comes to lubrication of hydrogel materials, though it has great potential applications in the field of industrial and medical drag reduction, some restrained properties are urgently needed to overcome for releasing the practical potential.

EXPERIMENTS

Durability of high lubrication was revealed from the sliding test during the long-term storage, as well as the long-distance sliding. Some variables which possibly affect the lubrication performance were examined to demonstrate that excellent lubricity of the coating would not be easily influenced by load, frequency, friction pair and temperature. The microstructure and mechanical characterization of the lubricative coating indicate that the resistance to harsh running conditions is premised on enough hydration extent and robustness. The formulae of Possion ratio and ball-on-disk contact stress which apply to soft matter were used for calculating contact stress values in tribology tests. Anti-swelling and bio-compatibility are also verified.

FINDINGS

This work found a route of achieving superior lubrication and coexisting with stability in lubrication, which can be used for drag reduction in medical devices and shipbuilding industry.

摘要

假设

水凝胶涂层在医疗器械、水处理膜、柔性电子和海洋防污等领域受到了广泛关注。然而,在水凝胶材料的润滑方面,尽管其在工业和医疗减阻领域具有巨大的潜在应用,但为了释放其实际潜力,一些受限的性能迫切需要克服。

实验

通过长期储存期间的滑动测试以及长距离滑动揭示了高润滑性的耐久性。研究了一些可能影响润滑性能的变量,以证明涂层的优异润滑性不易受到载荷、频率、摩擦副和温度的影响。润滑涂层的微观结构和力学表征表明,对恶劣运行条件的抗性是以足够的水合程度和坚固性为前提的。应用于软物质的泊松比和球盘接触应力公式用于计算摩擦学测试中的接触应力值。还验证了抗溶胀性和生物相容性。

发现

这项工作找到了一条实现卓越润滑并在润滑中保持稳定性的途径,可用于医疗器械和造船业的减阻。

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