Effects of different national standards and driving conditions on pollutants and persistent free radicals in diesel engine exhaust particles.

Exhaust pollutants from diesel vehicles constitute an important portion of air pollution. In addition to conventional pollutants such as carbon and nitrogen oxides, persistent free radicals (PFRs) exist on exhaust particles could also pose a health risk by inducing oxidative stress. However, recently there is a dearth of comprehensive studies addressing this concern. In this study, the exhaust particles emitted by tractors adhering to two prominent emission standards, namely GB III and GB I, that currently hold the largest tractor stocks, were collected under various working conditions. For the first time, this study dynamically monitored the characteristics of PFRs in exhaust particles emitted by internal combustion engines using biodiesel as fuel during driving on rural actual roads. Due to the stricter emission standard of GB III, which resulted in lower particle emissions, the concentration of PFRs emitted under the same fuel consumption was ultimately reduced. Noteworthily, while advancements like fuel atomization under engine electronic control unit (ECU) and the utilization of oxidation catalysts with low ignition temperature successfully decreased polycyclic aromatic hydrocarbons (PAHs) emission by altering combustion in the engine, they also resulted in heightened carbon structure defects, leading to a higher concentration of PFRs emitted per unit mass of particles. Additionally, compared to non-plowing driving conditions, localized hypoxia during plowing that could cause excessive fuel injection and uneven formation of fuel-air mixture resulted in the emission of a significant amount of carbon-containing substances with unstable structures. Consequently, this scenario led to an increased concentration of PFRs during plowing conditions. The results of this study demonstrated that the stricter emission standards and optimized technology could better reduce the concentration and types of PFRs in exhaust particles, reducing the environmental risk of exhaust particle, which is also of great significance for the realization of pollution reduction and carbon reduction goals.