• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利：CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法，用中文像聊天一样搜索，搜遍4000万医学文献。AI智能推荐，让科研检索更轻松。

立即免费搜索

文件翻译

保留排版，准确专业，支持PDF/Word/PPT等文件格式，支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述，25分钟生成高质量综述，智能提取关键信息，辅助科研写作。

立即免费体验

UiO - 66固定化金属有机框架与真菌对活性黑5的吸附及脱色研究

Adsorption and decolorization study of reactive black 5 by immobilized metal-organic framework of UiO-66 and fungus.

作者信息

Alkas Taufiq Rinda, Purnomo Adi Setyo, Ediati Ratna, Ersam Taslim

机构信息

Departement of Environment Management, Politeknik Pertanian Negeri Samarinda Samarinda 75131 Indonesia.

Department of Chemistry, Institut Teknologi Sepuluh Nopember (ITS) Surabaya 60111 Indonesia

出版信息

RSC Adv. 2023 Oct 20;13(44):30885-30897. doi: 10.1039/d3ra03804a. eCollection 2023 Oct 18.

DOI:10.1039/d3ra03804a
PMID:37869392
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC10588372/
Abstract

This study aimed to investigate immobilized metal-organic framework (MOF) UiO-66 and brown-rot fungus (GT) in PVA-SA matrices for adsorption and decolorization of reactive black 5 (RB5). Furthermore, UiO-66/GT@PVA-SA composite was successfully fabricated and obtained by immobilizing UiO-66 and GT mycelia into a mixture of PVA-SA. This composite demonstrated a decolorization ability of 80.12% for RB5 after 7 days. The composite's reusability was assessed for three cycles; at last, it only achieved 21%. This study reported that adsorption of RB5 by the composite followed a pseudo-second-order kinetic model with a correlation coefficient () of 0.9997. The Freundlich model was found to be suitable for the isotherm adsorption. The process was also spontaneous and feasible, as indicated by the negative Δ value. Subsequently, four metabolite products resulting from decolorization of RB5 by UiO-66/GT@PVA-SA composite were proposed, namely: CHNNaOS ( = 762), CHNOS ( = 353), CHNOS ( = 384), and CHOS ( = 325).

摘要

本研究旨在探究固定在聚乙烯醇-海藻酸钠（PVA-SA）基质中的金属有机框架（MOF）UiO-66和褐腐真菌（GT）对活性黑5（RB5）的吸附及脱色性能。此外，通过将UiO-66和GT菌丝体固定于PVA-SA混合物中，成功制备出UiO-66/GT@PVA-SA复合材料。该复合材料在7天后对RB5的脱色能力达80.12%。对该复合材料的可重复使用性进行了三个循环的评估；最终，其仅达到21%。本研究报告称，该复合材料对RB5的吸附遵循伪二级动力学模型，相关系数（）为0.9997。发现Freundlich模型适用于等温吸附。如负的Δ值所示，该过程也是自发且可行的。随后，提出了UiO-66/GT@PVA-SA复合材料对RB5脱色产生的四种代谢产物，即：CHNNaOS（ = 762）、CHNOS（ = 353）、CHNOS（ = 384）和CHOS（ = 325）。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c7fd/10588372/c5ce83cb7e68/d3ra03804a-f10.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c7fd/10588372/9f5f53db4023/d3ra03804a-f1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c7fd/10588372/422f2b7f4ced/d3ra03804a-f2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c7fd/10588372/23aad44a2fed/d3ra03804a-f3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c7fd/10588372/a55bd7173724/d3ra03804a-f5.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c7fd/10588372/4371459a291e/d3ra03804a-f6.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c7fd/10588372/c84b6e9bc634/d3ra03804a-f7.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c7fd/10588372/392fabccecd2/d3ra03804a-f8.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c7fd/10588372/fa80a89c1832/d3ra03804a-f9.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c7fd/10588372/c5ce83cb7e68/d3ra03804a-f10.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c7fd/10588372/9f5f53db4023/d3ra03804a-f1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c7fd/10588372/422f2b7f4ced/d3ra03804a-f2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c7fd/10588372/23aad44a2fed/d3ra03804a-f3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c7fd/10588372/a55bd7173724/d3ra03804a-f5.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c7fd/10588372/4371459a291e/d3ra03804a-f6.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c7fd/10588372/c84b6e9bc634/d3ra03804a-f7.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c7fd/10588372/392fabccecd2/d3ra03804a-f8.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c7fd/10588372/fa80a89c1832/d3ra03804a-f9.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c7fd/10588372/c5ce83cb7e68/d3ra03804a-f10.jpg

相似文献

1
Adsorption and decolorization study of reactive black 5 by immobilized metal-organic framework of UiO-66 and fungus.UiO - 66固定化金属有机框架与真菌对活性黑5的吸附及脱色研究
RSC Adv. 2023 Oct 20;13(44):30885-30897. doi: 10.1039/d3ra03804a. eCollection 2023 Oct 18.
2
Adsorption of methyl orange from aqueous solution with lignin-modified metal-organic frameworks: Selective adsorption and high adsorption capacity.木质素改性金属有机框架对水溶液中甲基橙的吸附：选择性吸附与高吸附容量
Bioresour Technol. 2023 Nov;388:129781. doi: 10.1016/j.biortech.2023.129781. Epub 2023 Sep 18.
3
One-step synthesis of functional metal organic framework composite for the highly efficient adsorption of tylosin from water.一步合成用于高效吸附水中泰乐菌素的功能性金属有机骨架复合材料。
J Colloid Interface Sci. 2021 Mar 15;586:269-278. doi: 10.1016/j.jcis.2020.10.090. Epub 2020 Oct 26.
4
Adsorptive removal of anionic dye (Reactive Black 5) from aqueous solution using chemically modified banana peel powder: kinetic, isotherm, thermodynamic, and reusability studies.用化学改性香蕉皮粉从水溶液中吸附去除阴离子染料（活性黑 5）：动力学、等温线、热力学和可重复使用性研究。
Int J Phytoremediation. 2020;22(3):267-278. doi: 10.1080/15226514.2019.1658709. Epub 2019 Aug 29.
5
Magnetic Nitrogen-Rich UiO-66 Metal-Organic Framework: An Efficient Adsorbent for Water Treatment.磁性富氮 UiO-66 金属有机骨架：一种用于水处理的高效吸附剂。
ACS Appl Mater Interfaces. 2023 Jun 28;15(25):30106-30116. doi: 10.1021/acsami.3c02171. Epub 2023 Jun 15.
6
Simple synthesis of chitosan/alginate/graphene oxide/UiO-67 amphoteric aerogels: Characterization, adsorption mechanism and application for removal of cationic and anionic dyes from complex dye media.壳聚糖/海藻酸钠/氧化石墨烯/UiO-67 两性水凝胶的简易合成：表征、吸附机理及用于从复杂染料介质中去除阳离子和阴离子染料的应用。
Int J Biol Macromol. 2023 Jul 1;242(Pt 1):124683. doi: 10.1016/j.ijbiomac.2023.124683. Epub 2023 May 2.
7
Selective Dye Adsorption by Zeolitic Imidazolate Framework-8 Loaded UiO-66-NH.负载UiO-66-NH的沸石咪唑酯骨架材料-8对染料的选择性吸附
Nanomaterials (Basel). 2019 Sep 8;9(9):1283. doi: 10.3390/nano9091283.
8
Investigation of a modified metal-organic framework UiO-66 with nanoscale zero-valent iron for removal of uranium (VI) from aqueous solution.采用纳米零价铁改性金属有机骨架 UiO-66 去除水溶液中铀（VI）的研究。
Environ Sci Pollut Res Int. 2020 Jun;27(16):20246-20258. doi: 10.1007/s11356-020-08381-4. Epub 2020 Apr 2.
9
Figuration of Zr-based MOF@cotton fabric composite for potential kidney application.Zr 基 MOF@棉织物复合材料的形态设计及其在潜在肾脏应用中的研究。
Carbohydr Polym. 2018 Sep 1;195:460-467. doi: 10.1016/j.carbpol.2018.04.122. Epub 2018 May 1.
10
Preparation and application of peptide molecularly imprinted material based on mesoporous metal-organic framework.基于介孔金属有机框架的肽分子印迹材料的制备与应用
Talanta. 2021 Mar 1;224:121765. doi: 10.1016/j.talanta.2020.121765. Epub 2020 Oct 10.

引用本文的文献

1
Adsorption and biodegradation of the azo dye methyl orange using immobilized in polyvinyl alcohol (PVA)-alginate-hectorite beads (BHec-RP).使用固定在聚乙烯醇（PVA）-海藻酸钠-锂皂石珠（BHec-RP）上对偶氮染料甲基橙进行吸附和生物降解。
RSC Adv. 2024 Jun 7;14(26):18277-18290. doi: 10.1039/d3ra08692e. eCollection 2024 Jun 6.

本文引用的文献

1
Selective adsorption of anionic and cationic dyes on mesoporous UiO-66 synthesized using a template-free sonochemistry method: kinetic, isotherm and thermodynamic studies.采用无模板声化学法合成的介孔UiO-66对阴离子和阳离子染料的选择性吸附：动力学、等温线及热力学研究
RSC Adv. 2023 Apr 20;13(18):12320-12343. doi: 10.1039/d2ra06947d. eCollection 2023 Apr 17.
2
Hectorite-CTAB-alginate composite beads for water treatment: kinetic, isothermal and thermodynamic studies.用于水处理的锂皂石-十六烷基三甲基溴化铵-海藻酸盐复合珠：动力学、等温线和热力学研究
RSC Adv. 2023 Jan 3;13(2):790-801. doi: 10.1039/d2ra06934b.
3
Equilibrium and Kinetic Modeling of Crystal Violet Dye Adsorption by a Marine Diatom, .
海洋硅藻对结晶紫染料吸附的平衡与动力学建模
Materials (Basel). 2022 Sep 14;15(18):6375. doi: 10.3390/ma15186375.
4
Optimization of the Decolorization of the Reactive Black 5 by a Laccase-like Active Cell-Free Supernatant from .来自……的类漆酶活性无细胞上清液对活性黑5脱色的优化
Microorganisms. 2022 May 31;10(6):1137. doi: 10.3390/microorganisms10061137.
5
Thermal degradation of defective high-surface-area UiO-66 in different gaseous environments.在不同气体环境中缺陷型高比表面积UiO-66的热降解
RSC Adv. 2021 Dec 3;11(61):38849-38855. doi: 10.1039/d1ra05411b. eCollection 2021 Nov 29.
6
Decolourisation of textile dye by laccase: Process evaluation and assessment of its degradation bioproducts.漆酶对纺织染料的脱色：工艺评估及其降解生物产物的评价。
Bioresour Technol. 2021 Nov;340:125591. doi: 10.1016/j.biortech.2021.125591. Epub 2021 Jul 14.
7
Decolorization and discovery of metabolic pathway for the degradation of Mordant Black 11 dye by Klebsiella sp. MB398.解偶氮染料媒介黑 11 的降解菌 Klebsiella sp. MB398 的脱色及其代谢途径解析。
Braz J Microbiol. 2021 Jun;52(2):761-771. doi: 10.1007/s42770-021-00470-x. Epub 2021 Mar 22.
8
Utilization of red mud waste into mesoporous ZSM-5 for methylene blue adsorption-desorption studies.将赤泥废料用于制备介孔ZSM-5以进行亚甲基蓝吸附-解吸研究。
Environ Sci Pollut Res Int. 2021 Jul;28(28):37354-37370. doi: 10.1007/s11356-021-13285-y. Epub 2021 Mar 13.
9
Simulating the synergy of electron donors and different redox mediators on the anaerobic decolorization of azo dyes: Can AQDS-chitosan globules replace the traditional redox mediators?模拟电子供体与不同氧化还原介体对偶氮染料厌氧脱色的协同作用：AQDS-壳聚糖珠粒能否替代传统氧化还原介体？
Chemosphere. 2021 Jul;275:130025. doi: 10.1016/j.chemosphere.2021.130025. Epub 2021 Feb 20.
10
Modeling and optimization of simultaneous degradation of rhodamine B and acid red 14 binary solution by homogeneous Fenton reaction: a chemometrics approach.均相芬顿反应同时降解罗丹明B和酸性红14二元溶液的建模与优化：一种化学计量学方法
Turk J Chem. 2020 Aug 18;44(4):987-1001. doi: 10.3906/kim-2002-59. eCollection 2020.