用亚硝酸钠/碘进行烯烃的自由基硝化反应。
A free radical nitration of olefins with NaNO/IO.
作者信息
Huang Xuan, You Huichao, Fang Fang, Wang Fan, Liu Zhong-Quan
机构信息
Jiangsu Collaborative Innovation Center of Chinese Medicinal Resources Industrialization, College of Pharmacy, Nanjing University of Chinese Medicine, Nanjing 210023, P. R. China.
出版信息
Chem Commun (Camb). 2023 Nov 7;59(89):13352-13354. doi: 10.1039/d3cc04275h.
PMID:37872833
Abstract
We demonstrated herein an IO-mediated radical nitration of olefins with NaNO. A variety of ()-nitroolefins can be synthesized in high yields and chemoselectivity.
摘要
我们在此展示了通过碘介导的烯烃与亚硝酸钠的自由基硝化反应。多种（）-硝基烯烃能够以高产率和化学选择性合成。
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